Abstract
Tris-(8-hydroxyquinolates) of aluminum(iii), chromium(iii), and iron(iii) in the presence of triphenylphosphine oxide efficiently catalyze the formation of alkylenecarbonates by the reaction of CO2 with oxiranes, viz., propylene oxide, but-2-ene oxides, and isobutylene oxide. The catalytic system is active at 140—170 °C and a CO2 pressure of 15—100 atm.
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Lermontov, S.A., Velikokhat"ko, T.N., Golovin, E.Y. et al. 8-Hydroxyquinolates of trivalent metals as new catalysts for the reaction of CO2 with epoxides. Russian Chemical Bulletin 51, 836–838 (2002). https://doi.org/10.1023/A:1016041002506
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DOI: https://doi.org/10.1023/A:1016041002506