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Apparent Molar Volumes of Multicharged Cations in Dimethyl Sulfoxide Solutions at 25°C

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Abstract

Densities for DMSO solutions of iron(III), aluminium(III), beryllium(II) and magnesium(II) perchlorates and silver nitrate are reported. Densities for DMSO solutions of tetraethylammonium perchlorate and nitrate and tetrabutylammonium perchlorate and tetraphenylborate are also presented. The partial molar volumes of the DMSO-solvated cations are derived and discussed in terms of variation with the charge number.

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References

  1. W. Libuś, B. Chachulski, W. Grzybkowski, M. Pilarczyk, and D. Puchalska, J. Solution Chem. 10, 631(1981).

    Google Scholar 

  2. W. Libuś, W. Grzybkowski, and R. Pastewski, J. Chem. Soc., Faraday Trans. 1 77, 147(1981).

    Google Scholar 

  3. D. Bobicz and W. Grzybkowski, J. Solution Chem. 27, 815(1998).

    Google Scholar 

  4. Ch. Atlani and J.-C. Justice, J. Solution Chem. 4, 955(1975).

    Google Scholar 

  5. D. O. Masson, Phil. Mag. 8, 218(1929).

    Google Scholar 

  6. O. Redlich and P. Rosenfeld, Z. Phys. Chem. A, 155, 65(1931).

    Google Scholar 

  7. B. E. Conway, J. Solution Chem. 7, 721(1978).

    Google Scholar 

  8. F. J. Millero, in Water and Aqueous Solutions, R. A. Horne ed. (Wiley, New York, 1972).

    Google Scholar 

  9. Y. Marcus, G. Hefter, and T. Pang, J. Chem. Soc., Faraday Trans. 90, 1899(1994).

    Google Scholar 

  10. G. Hefter and Y. Marcus, J. Solution Chem. 26, 249(1997).

    Google Scholar 

  11. Y. Tsutsui, K. Sugimoto, H. Wasada, Y. Inada, and S. Funahashi, J. Phys. Chem. A 101, 2900(1997).

    Google Scholar 

  12. S. F. Lincoln and M. N. Tkaczuk, Ber. Bunsenges. Phys. Chem. 85, 433(1981).

    Google Scholar 

  13. I. S. Perelygin and V. S. Osipov, Russ. J. Phys. Chem. 56, 1036(1979).

    Google Scholar 

  14. L. G. Hepler, J.Phys.Chem. 61, 1426(1957).

    Google Scholar 

  15. Y. Marcus, J. Chem. Soc., Faraday Trans. 89, 713(1993).

    Google Scholar 

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Bobicz, D., Grzybkowski, W. Apparent Molar Volumes of Multicharged Cations in Dimethyl Sulfoxide Solutions at 25°C. Journal of Solution Chemistry 31, 223–234 (2002). https://doi.org/10.1023/A:1015820909595

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  • DOI: https://doi.org/10.1023/A:1015820909595

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