Abstract
High-molecular-weight products containing 4.21-10.4% bound sulfur that are soluble (32-86%) in aqueous alkaline solutions are obtained from xanthogenation of lignocarbohydrates by carbon disulfide in the presence of NaOH in propan-2-ol. The degree of preliminary alkaline activation of the raw material in propan-2-ol has the principal effect on the composition and physicochemical properties of the xanthogenation products.
Similar content being viewed by others
REFERENCES
E. M. Mogilevskii, in: Chemical Fibers, A. A. Konkina, ed., VNIIV, Moscow (1968).
Z. A. Rogovin, Chemical Principles of Artificial Fiber Production [in Russian], Khimiya, Moscow (1974), Vol. 1.
U.S. Pat. No. 3469969 (1969); Ref. Zh. Khim., 10T123P (1970).
Z. A. Rogovin, Chemistry of Cellulose [in Russian], Khimiya, Moscow (1972).
A. B. Pakshver, E. Z. Kipershlak, A. V. Danyukova, et al., Khim. Volokna pp, 43 (1987).
A. T. Serkov and L. A. Vol′f, Khim. Volokna pp, 25 (1984).
M. V. Efanov, Candidate Dissertation in Chemical Sciences, Siberian State Technical Univ., Krasnoyarsk (1999).
V. A. Klimova, Basic Analytical Micromethods for Organic Compounds [in Russian], Khimiya, Moscow (1975).
A. B. Pakshver, ed., Handbook of Analytical Monitoring for Production of Artificial and Synthetic Fibers [in Russian], Gizlegprom, Moscow (1957).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Efanov, M.V., Pershina, L.A. Xanthogenation of Lignocarbohydrates by Carbon Disulfide. Chemistry of Natural Compounds 38, 90–94 (2002). https://doi.org/10.1023/A:1015750203239
Issue Date:
DOI: https://doi.org/10.1023/A:1015750203239