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A Zn(II) ion-selective electrode based on chalcogenide As2Se3–Sb2Se3–ZnSe and GeSe2–ZnSe–ZnTe glasses

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Abstract

Zn(II) ion-selective electrodes with chalcogenide glassy As2Se3–Sb2Se3–ZnSe and GeSe2–ZnSe–ZnTe membranes were developed. Basic analytical characteristics such as stability, linearity, slope of the electrode function, limits of detection, effect of pH on the electrode potential and response time were studied with varying glass compositions. A structural mechanism for explanation of the dependencies obtained is suggested.

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Authors and Affiliations

  1. Department of Semiconductors, University of Chemical Technology and Metallurgy, 1756, Sofia, Bulgaria

    S.V. Boycheva & V.S. Vassilev

  2. Institute of Solid State Physics, Bulgarian Academy of Sciences, 1784, Sofia, Bulgaria

    Z.G. Ivanova

Authors
  1. S.V. Boycheva
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  2. V.S. Vassilev
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  3. Z.G. Ivanova
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Correspondence to S.V. Boycheva.

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Boycheva, S., Vassilev, V. & Ivanova, Z. A Zn(II) ion-selective electrode based on chalcogenide As2Se3–Sb2Se3–ZnSe and GeSe2–ZnSe–ZnTe glasses. Journal of Applied Electrochemistry 32, 281–285 (2002). https://doi.org/10.1023/A:1015589614235

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  • DOI: https://doi.org/10.1023/A:1015589614235

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