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Synthesis and the crystal structure of the triosmium cluster with the μ-dehydrobenzene ligand, Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}

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Abstract

The Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph} complex, which was isolated from the products of thermolysis of Os3(CO)10(μ-dppm) (dppm is Ph2PCH2PPh2) in toluene, was characterized by X-ray diffraction analysis. Protonation of the resulting complex with trifluoroacetic acid afforded the cationic complex [Os3(μ-H)3(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}]+.

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References

  1. C. W. Bradford and R. S. Nyholm, J. Chem. Soc., Dalton Trans., 1973, 529.

  2. A. J. Deeming, S. E. Kabir, N. I. Powell, P. A. Bates, and M. B. Hursthouse, J. Chem. Soc., Dalton Trans., 1987, 1529.

  3. N. Lugan, J. J. Bonnet, and J. A. Ibers, J. Am. Chem. Soc., 1985, 107, 4484.

    Google Scholar 

  4. M. I. Bruce, G. Shaw, and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1972, 2094.

  5. A. A. Koridze, V. I. Zdanovich, V. Yu. Lagunova, M. G. Ezernitskaya, P. V. Petrovskii, Z. A. Starikova, F. M. Dolgushin, and A. I. Yanovsky, Izv. Akad. Nauk, Ser. Khim., 1999, 1206 [Russ. Chem. Bull., 1999, 48, 1192 (Engl. Transl.)].

    Google Scholar 

  6. M. I. Bruce, B. W. Skelton, A. H. White, and N. N. Zaitseva, Inorg. Chem. Commun., 1999, 2, 17.

    Google Scholar 

  7. J. A. Clucas, D. F. Forster, M. M. Harding, and A. K. Smith, J. Chem. Soc., Chem. Commun., 1984, 949.

  8. R. D. Adams and N. M. Golembeski, J. Organomet. Chem., 1979, 172, 239.

    Google Scholar 

  9. M. I. Bruce, J. M. Guss, R. Mason, B. W. Skelton, and A. H. White, J. Organomet. Chem., 1983, 251, 261.

    Google Scholar 

  10. R. G. Goudsmit, B. F. G. Johnson, J. Lewis, P. R. Raithby, and M. J. Rosales, J. Chem. Soc., Dalton Trans., 1983, 2257.

  11. S. Cartwright, J. A. Clucas, R. H. Dawson, D. F. Foster, M. M. Harding, and A. K. Smith, J. Organomet. Chem., 1986, 302, 403.

    Google Scholar 

  12. SMART V5.051 and SAINT V5.00, Area Detector Control and Integration Software, Bruker AXS Inc., Madison (USA), 1998.

  13. G. M. Sheldrick, SADABS, Program for the Empirical Absorption Correction of Area Detector Data, University of Göttingen, Göttingen (Germany), 1998.

    Google Scholar 

  14. G. M. Sheldrick, SHELXTL-97. Version 5.10, Bruker AXS Inc., Madison (USA), 1997.

    Google Scholar 

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Authors and Affiliations

  1. Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. A. Koridze, S. A. Kuklin, P. V. Petrovskii, F. M. Dolgushin & M. G. Ezernitskaya

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  1. A. A. Koridze
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  2. S. A. Kuklin
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  3. P. V. Petrovskii
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  4. F. M. Dolgushin
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  5. M. G. Ezernitskaya
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Koridze, A.A., Kuklin, S.A., Petrovskii, P.V. et al. Synthesis and the crystal structure of the triosmium cluster with the μ-dehydrobenzene ligand, Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}. Russian Chemical Bulletin 51, 350–353 (2002). https://doi.org/10.1023/A:1015428331850

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