Abstract
The thermochemical characteristics of solution of copper(II) chloride in the mixed solvent waterhexamethylphosphoric triamide were obtained from calorimetric data, and corresponding solvation characteristics were calculated. The enthalpy characteristics of solvation of the Cu2 + ion in this solvent were obtained and discussed.
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REFERENCES
Beck, M.T., Chemistry of Complex Equilibria, Budapest: Akad. Kiado, 1970
Krestov, G.A., Termodinamika ionnykh protsessov v rastvorakh (Thermodynamics of Ionic Processes in Solutions), Leningrad: Khimiya, 1984
Vandyshev, V.N., Korolyov, V.P., and Krestov, G.A., Thermochim. Acta, 1990, vol. 169, no. 1, pp. 57-63
Mikheev, S.I., Sharnin, V.A., and Shormanov, V.A., Zh. Fiz. Khim., 1993, vol. 67, no. 7, pp. 1776-1778
Gusev, V.D., Shormanov, V.A., and Krestov, G.A., Zh. Fiz. Khim., 1982, vol. 56, no. 10, pp. 2499-2502
Devyatov, F.V., Safina, V.F., Lazareva, L.G., and Sal'nikov, Yu.I., Zh. Neorg. Khim., 1993, vol. 38, no. 6, pp. 1085-1088
Korolyov, V.P., Vandyshev, V.N., and Krestov, G.A., Thermochim. Acta, 1993, vol. 214, no. 1, pp. 203-210
Solov'ev, S.N., Privalov, N.M., and Vorob'ev, A.F., Zh. Fiz. Khim., 1976, vol. 50, no. 11, pp. 2719-2726
Termodinamicheskie kharakteristiki nevodnykh rastvorov electrolitov: Spravochnik (Thermodynamic Properties of Nonaqueous Electrolyte Solutions: Handbook), Poltoratskii, G.M., Ed., Moscow: Khimiya, 1984
Vandyshev, V.N. and Serebryakova, A.L., Abstracts of Papers, 7th Int. Conf. “The Problems of Solvation and Complex Formation in Solutions,” Ivanovo, 1998, p. 332
Manin, N.G. and Korolev, V.P., Zh. Neorg. Khim., 1999, vol. 44, no. 8, pp. 1332-1337
Vandyshev, V.N. and Serebryakova, A.L., Zh. Obshch. Khim., 1997, vol. 67, no. 4, pp. 579-583
Vandyshev, V.N. and Serebryakova, A.L., Zh. Obshch. Khim., 1998, vol. 68, no. 6, pp. 915-919
Mayer, U., Gerger, W., and Gutman, V., Monatsh. Chem., 1977, vol. 44, no. 6, pp. 673-678
Korolyev, V.P., Batov, D.V., Vandyshev, V.N., and Krestov, G.A., Zh. Fiz. Khim., 1983, vol. 57, no. 1, pp. 253-255
Vandyshev, V.N. and Serebryakova, A.L., Abstracts of Papers, 2 Mezhdunarodnaya nauchno-tekhnicheskaya konferentsiya “Aktual'nye problemy khimii i khimicheskoi tekhnologii” (2nd Int. Scientific and Technical Conf. “Actual Problems of Chemistry and Chemical Technology,” Ivanovo, 1997, p. 39
Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veschestva (Pure Chemical Substances), Moscow: Khimiya, 1974
Gordon, A.J. and Ford, R.A., The Chemist's Companion, New York: Wiley, 1972
Lur'e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook on Analytical Chemistry), Moscow: Khimiya, 1967.
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Vandyshev, V.N., Serebryakova, A.L. Thermochemistry of Solution and Solvation of CuCl2 in Water-Hexamethylphosphoric Triamide Mixtures at 298 K. Russian Journal of General Chemistry 72, 28–31 (2002). https://doi.org/10.1023/A:1015372607586
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DOI: https://doi.org/10.1023/A:1015372607586