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Synthesis of new macrocyclic aminomethylphosphines based on 4,4"-diaminodiphenylmethane and its derivatives

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Abstract

The reaction of bis(hydroxymethyl)phenylphosphine with 4,4"-diaminodiphenylmethane in DMF afforded 1,1",5,5"-bis[methylenedi(p-phenylene)]di(3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) (1) whose structure was established by X-ray diffraction analysis. Sulfurization and oxidation of macrocyclic tetraphosphine 1 gave rise to products 2 and 3, respectively, compound 3 being obtained as a stable hexahydrate. The reaction of bis(hydroxymethyl)phenylphosphine with bis(4-N-methylaminophenyl)methane in DMF followed by sulfurization yielded monocyclic bis{methylenedi[p-phenylene(N-methyl)aminomethyl]}di(P-phenyl)phosphine sulfide (4).

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Authors and Affiliations

  1. Kazan Research Center of the Russian Academy of Sciences, A. E. Arbuzov Institute of Organic and Physical Chemistry, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    R. M. Kuznetsov, A. S. Balueva, I. A. Litvinov, A. T. Gubaidullin, G. N. Nikonov, A. A. Karasik & O. G. Sinyashin

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  1. R. M. Kuznetsov
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  2. A. S. Balueva
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  3. I. A. Litvinov
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  4. A. T. Gubaidullin
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  5. G. N. Nikonov
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  6. A. A. Karasik
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  7. O. G. Sinyashin
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Kuznetsov, R.M., Balueva, A.S., Litvinov, I.A. et al. Synthesis of new macrocyclic aminomethylphosphines based on 4,4"-diaminodiphenylmethane and its derivatives. Russian Chemical Bulletin 51, 151–156 (2002). https://doi.org/10.1023/A:1015086419302

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  • DOI: https://doi.org/10.1023/A:1015086419302

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