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Induced aromaticity

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Abstract

The influence of counterions on the stabilization of three-, five-, and six-membered cyclic organic and organoboron systems was studied by the ab initio (MP2(full)/6-311+G**) and density functional (B3LYP/6-311+G**) methods. The structures of molecular charge-transfer molecular complexes formed by the interaction with counterions are predicted. A crucial role of counterions in the stabilization of aromatic systems that are unstable in themselves was revealed. Stabilization of these systems involves both charge transfer and covalent bonding.

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Authors and Affiliations

  1. Institute of Physical and Organic Chemistry at Rostov State University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    R. M. Minyaev, V. I. Minkin, A. G. Starikov & T. N. Gribanova

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  1. R. M. Minyaev
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  2. V. I. Minkin
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  3. A. G. Starikov
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  4. T. N. Gribanova
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Minyaev, R.M., Minkin, V.I., Starikov, A.G. et al. Induced aromaticity. Russian Chemical Bulletin 50, 2325–2335 (2001). https://doi.org/10.1023/A:1015067025720

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