Skip to main content
SpringerLink
Log in

Dubinin"s theory and its contribution to adsorption science

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Dubinin"s theory for the volume filling of micropores (TVFM), originally developed for the adsorption of single vapours by microporous solids such as activated carbons and zeolites, has gradually been extended to other areas. They include immersion calorimetry, the adsorption of water vapour and of mixtures, as well as adsorption from aqueous solutions. Recent studies in the field of adsorption from aqueous solutions, by activated carbons, suggest that the principle of temperature invariance is fulfilled and in the case of phenolic compounds a modified DRK equation can be used to predict the adsorption equilibrium over a certain range of temperatures. Computer modelling of CO2 adsorption by carbons at 273 K leads to micropore distributions, which are in good agreement with those derived from other techniques. It also appears that the model isotherms in single slit-shaped micropores can be fitted to the Hill-de Boer isotherm, in agreement with mathematical studies of the origin of the Dubinin—Astakhov equation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. M. Dubinin, E. D. Zaverina, and L. V. Radushkevich, Zh. Fiz. Khim., 1947, 21, 1351 [J. Phys. Chem. USSR, 1947, 21 (Engl. Transl.)].

    Google Scholar 

  2. M. Polanyi, Z. Elektrochem., 1920, 26, 370.

    Google Scholar 

  3. M. M. Dubinin, in Progress in Surface Science and Membrane Science, Ed. D. A. Cadenhead, Academic Press, New York, 1975, 9, 1.

    Google Scholar 

  4. M. M. Dubinin and F. Stoeckli, J. Colloid Interface Sci., 1980, 75, 34.

    Google Scholar 

  5. M. M. Dubinin, Carbon, 1989, 27, 457.

    Google Scholar 

  6. M. M. Dubinin, N. S. Polyakov, and L. I. Kataeva, Carbon, 1991, 29, 481.

    Google Scholar 

  7. F. Stoeckli, Adsorpt. Sci. Technol., 1993, 10, 3.

    Google Scholar 

  8. Adsorpt. Sci. Technol., Ed. F. R. G. Gimblett, 1993, 10 (special issue).

  9. F. Stoeckli, in Porosity in Carbons-Characterization and Application, Ed. J. Patrick, Arnold, London, 1995, 67.

    Google Scholar 

  10. Yu. K. Tovbin, Izv. Akad. Nauk, Ser. Khim., 1998, 659 [Russ. Chem. Bull., 1998, 47, 637 (Engl. Transl.)].

  11. V. Kh. Dobrushkin, Langmuir, 1998, 14, 3840.

    Google Scholar 

  12. E. A. Ustinov, N. S. Polyakov, and G. A. Petukhova, Izv. Akad. Nauk, Ser. Khim., 1999, 261 [Russ. Chem. Bull., 1999, 48, 261 (Engl. Transl.)].

    Google Scholar 

  13. F. Stoeckli, Carbon, 1997, 36, 363.

    Google Scholar 

  14. F. Stoeckli, Izv. Akad. Nauk SSSR, Ser. Khim., 1981, 63 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981, 30, No. 1 (Engl. Transl.)].

  15. A. Lavanchy, M. Stoeckli, C. Wirz, and F. Stoeckli, Adsorpt. Sci. Technol., 1996, 13, 537.

    Google Scholar 

  16. F. Stoeckli, D. Wintgens, A. Lavanchy, and M. Stoeckli, Adsorpt. Sci. Technol., 1997, 15, 677.

    Google Scholar 

  17. F. Stoeckli, M. V. López-Ramón, and C. Moreno-Castilla, Langmuir, 2001, 17, 3301.

    Google Scholar 

  18. F. Stoeckli, T. S. Jakubov, and A. Lavanchy, J. Chem. Soc., Faraday Trans., 1994, 90, 783.

    Google Scholar 

  19. G. O. Wood, Carbon, 1992, 30, 593.

    Google Scholar 

  20. M. M. Dubinin, G. M. Plavnik, and E. D. Zaverina, Carbon, 1964, 2, 261.

    Google Scholar 

  21. Carbon, Fundamental Aspects of Active Carbons, Eds. B. Mc. Enaney, T. Mays, and F. Rodrigues-Reinoso, 1998, 36,No. 10 (special issue).

    Google Scholar 

  22. F. Stoeckli, A. Guillot, A. M. Slasli, and D. Hugi-Cleary, Carbon, 2000, 38, 938.

    Google Scholar 

  23. M. A. Daley, D. Tandon, J. Economy, and E. J. Hippo, Carbon, 1996, 34, 1191.

    Google Scholar 

  24. G. M. Kaganer, Dokl. Akad. Nauk SSSR, 1952 [Dokl. Chem., 1952, 116, 603 (Engl. Transl.)].

  25. F. Stoeckli, D. Hugi-Cleary, and T. A. Centeno, J. Europ. Ceramic Soc., 1998, 18, 1177.

    Google Scholar 

  26. D. Hugi-Cleary and F. Stoeckli, Carbon, 2000, 38, 1309.

    Google Scholar 

  27. W. Rudzinski and D. H. Everett, Adsorption of Gases on Heterogeneous Surfaces, Academic Press, New York, 1992, 95; 124.

    Google Scholar 

  28. M. V. López-Ramón, J. Jagiello, T. J. Bandosz, and N. A. Seaton, Langmuir, 1997, 13, 4435.

    Google Scholar 

  29. J. Jagiello and J. Schwarz, Langmuir, 1993, 9, 2513.

    Google Scholar 

  30. J. Jagiello, T. J. Bandosz, and J. Schwarz, Langmuir, 1996, 12, 2837.

    Google Scholar 

  31. B. P. Bering and V. V. Serpinskii, Zh. Fiz. Khim., 1952, 26, 253 [J. Phys. Chem. USSR, 1952, 26 (Engl. Transl.)].

    Google Scholar 

  32. A. L. Myers and J. M. Prausnitz, AIChE J., 1965, 11, 121.

    Google Scholar 

  33. F. Stoeckli, G. Couderc, A. Lavanchy, D. Wintgens, and Ph. Girardin, Adsorpt. Sci. Technol., 2000, 18, 581.

    Google Scholar 

  34. A. Lavanchy and F. Stoeckli, Carbon, 1997, 35, 1573.

    Google Scholar 

  35. A. Guillot and F. Stoeckli, Carbon, 2001, 39, 2059.

    Google Scholar 

  36. M. M. Dubinin and V. V. Serpinskii, Carbon, 1981, 19, 402.

    Google Scholar 

  37. N. S. Polyakov, G. A. Petukhova, F. Stoeckli, T. Chenteno, and A. Lavanshy, Izv. Akad. Nauk, Ser. Khim., 1996, 1132 [Russ. Chem. Bull., 1996, 45, 1071 (Engl. Transl.)].

    Google Scholar 

  38. F. Stoeckli and A. Lavanchy, Carbon, 2000, 38, 475.

    Google Scholar 

  39. M. V. López-Ramón, F. Stoeckli, C. Moreno-Castilla, and F. Carrasco-Marín, Langmuir, 2000, 16, 5967.

    Google Scholar 

  40. A. Lavanchy and F. Stoeckli, Carbon, 1999, 37, 315.

    Google Scholar 

  41. M. Jaroniec and A. Derylo, J. Colloid Interface Sci., 1981, 84, 191.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department of the University, Bellevaux 51, CH-2007, Neuchatel, Switzerland

    F. Stoeckli

Authors
  1. F. Stoeckli
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stoeckli, F. Dubinin"s theory and its contribution to adsorption science. Russian Chemical Bulletin 50, 2265–2272 (2001). https://doi.org/10.1023/A:1015054922994

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1015054922994

Search

Navigation