Abstract
A modified method for the synthesis of derivatives of pyrrolizinedione and indolizinedione was proposed. The method is based on the intramolecular cyclization of keto-stabilized sulfur ylides generated in situ from diazo ketones and Me2S in the presence of Rh2(OAc)4.
Similar content being viewed by others
References
V. K. Mavrodiev, I. I. Furlei, S. N. Lakeev, F. Z. Galin, and G. A. Tolstikov, Izv. Akad. Nauk, Ser. Khim., 1999, 2100 [Russ. Chem. Bull., 1999, 48, 2077 (Engl. Transl.)].
G. A. Tolstikov, F. Z. Galin, S. N. Lakeev, L. M. Khalilov, and V. S. Sultanova, Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 612 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 39, 535 (Engl. Transl.)].
F. Z. Galin, S. N. Lakeev, and G. A. Tolstikov, Izv. Akad. Nauk, Ser. Khim., 1996, 165 [Russ. Chem. Bull., 1996, 45, 156 (Engl. Transl.)].
A. Padwa and S. F. Hornbuckle, Chem. Rev., 1991, 91, 263.
L. M. Zubritskii, Gomogenno-kataliticheskie reaktsii nepredel´nykh soedinenii [Gomogeneous-Catalytic Reactions of Unsaturated Compounds], Izd-vo LTI, Leningrad, 1987, 85 (in Russian).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lakeev, S.N., Mullagalin, I.Z., Maidanova, I.O. et al. Sulfur ylides. 10. Modified method for the synthesis of pyrrolizine- and indolizinediones. Russian Chemical Bulletin 51, 189–190 (2002). https://doi.org/10.1023/A:1015054907007
Issue Date:
DOI: https://doi.org/10.1023/A:1015054907007