Abstract
Very uniformly distributed Ni/MgO catalyst islands patterned on a silicon substrate were obtained using the microcontact printing (μ CP) technique. The catalyst precursor solution contained the component metal nitrates, citric acid, water and 2-propanol. The size, thickness and composition of the catalyst islands are tunable and controllable. The carbon deposition reaction was conducted on the patterned catalyst islands. This μ CP technique is flexible to pattern catalyst islands with and without supports.
Similar content being viewed by others
References
G.A. Somorjai, in: Introduction to Surface Chemistry and Catalysis (Wiley Interscience, New York, 1994) p. 465.
F.H. Ribeiro and G.A. Somorjai, in: Handbook of Heterogenerous Catalysis, eds. G. Ertl, H. Knözinger and J. Weitkamp (VCH Publishers, Weinheim, 1996).
P.W. Jacobs, F.H. Ribeiro, G.A. Somorjai and S.J. Wind, Catal. Lett. 37 (1996) 131.
S. Subramoney, Adv. Mater. 10,15 (1998) 1157.
J. Kong, H.T. Soh, A.M. Cassell, C.F. Quate and H. Dai, Nature 395 (1998) 878.
S. Fan, M.G. Chapline, N.R. Franklin, T.W. Tombler, A.M. Cassell and H. Dai, Science 283 (1999) 512.
G. Zheng, H. Zhu, Q. Luo, Y. Zhou, D. Zhao, Chem. Mater. 13 (2001) 2240.
S. Huang, A.W.H. Mau, T.W. Turney, P.A. White and L. Dai. J. Phys. Chem. B 104 (2000) 2193.
M. Remskar, A. Mrzel, Z. Skraba, A. Jesih, M. Ceh, J. Demsar, P. Stadelmann, F. Lěvy and D. Mihailovic, Science 292 (2001) 479.
R.R. Schlitter, J.W. Seo, J.K. Gimzewski, C. Durkan, M.S.M. Saifullah and M.E. Welland, Science 292 (2001) 1136.
Z.W. Pan, Z.R. Dai and Z.L. Wang, Science 291 (2001) 1947.
Y. Xia and G.M. Whitesides, Annu. Rev. Mater. Sci. 28 (1998) 153.
Y. Xia, J.A. Rogers, K. Paul and G.M. Whitesides, Chem. Rev. 99 (1999) 1823.
J. Aizenberg, A.J. Black and G.M. Whitesides, Nature 398 (1999) 495.
Z.Y. Zhong, B. Gates, Y. Xia and D. Qin, Langmuir 16 (2000) 10369.
Z.Y. Zhong, L.G. Chen, Q.Y. Yan and X.C. Fu, Studies in Surface Science and Catalysis 919 (1995) 647.
Z.Y. Zhong, H. Chen, S. Tang, J. Ding, J. Lin and K.L. Tan, Chem. Phys. Lett. 330 (2000) 41.
J. Kastner, T. Pichler, H. Kazmany, S. Curran, W. Blau, D.N. Weldon, M. Delamesiere, S. Draper and H. Zandbergen, Chem. Phys. Lett. 221 (1994) 539.
P.H. Tang, S.L. Zhang, K.T. Yue, F.M. Huang, Z.J. Shi, X.H. Zhou and Z.N. Gu, J. Raman Spectroscopy 28 (1997) 369.
H. Kind, J.M. Bonard, C. Emmenegger, L.O. Nisson, K. Hernadi, E. Maillard-Schaller and L. Forró, Adv. Mater. 11,15 (1999) 1285.
H. Kind, J.M. Bonard, L. Forró and K. Kern, Langmuir 16 (2000) 6887.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zhong, Z., Chen, H., Tang, S. et al. Miniaturizing Catalytic Reaction on Patterned Catalyst Islands. Catalysis Letters 78, 325–329 (2002). https://doi.org/10.1023/A:1014948332423
Issue Date:
DOI: https://doi.org/10.1023/A:1014948332423