Abstract
In an attempt to improve the understanding of the electrochemical effects observed on an original potentiometric gas sensor, interactions of oxygen with the device were investigated. These calorimetric measurements have evidenced the existence of a weakly bounded endothermal oxygen species. Moreover these species may be regarded to be responsible for the electrical response developed by the sensor. Such results, which are in agreement with a previously proposed model, validate the underlying hypothesis and shed light on the role of oxygen in the sensor’s responses.
Similar content being viewed by others
References
R. Lalauze, E. Visconte, L. Montanaro and C. Pijolat, Sensors and Actuators B, 13.14 (1993) 241.
C. Pijolat, C. Pupier, C. Testud, R. Lalauze, L. Montanaro, A. Negro and C. Malvicino, J. Electroceramics, 2.3 (1998) 181.
Brite EuRam Contract Community, Project Econox, no BE 7058.
Brite EuRam III Contract Community, Project Econox II, no BE 97-4028.
C. Pupier, C. Pijolat, J. C. Marchand and R. Lalauze, J. Electrochem. Soc., 146 (1999) 2360.
N. Li, T. C. Tan and H. C. Zeng, J. Electrochem. Soc., 140 (1993) 1068.
C. Pupier, PhD Thesis, ENSMSE-INPG, 1999.
G. Colucci, A. Negro, E. Visconte, C. Pijolat and R. Lalauze, Ceram. Int., 6 (1990) 225.
B. L. Kuzin and M. A. Kamarov, Solid state ionics, 39 (1990) 163.
B. C. Nguyen, L. M. Rinco-Rubio and D. M. Mason, J. Electrochem. Soc., 133 (1986) 1860.
J. E. Bauerle, J. Phys. Chem. Solids, 30 (1969) 2657.
A. Bielanski and J. Haber, Catal. Rev. Sci. Eng., 19 (1979) 1.
G. Heiland and D. Kohl, Chemical Sensor Technology, 1 (1988) 15.
D. Khol, Sensors and Actuators, 18 (1989) 71.
S. R. Morrison, The Chemical Physics of Surfaces, Plenum Press, 1990, 1977.
C. Schwandt and W. Weppner, J. Electrochem. Soc., 144 (1997) 3728.
H. S. Isaacs and L. J. Olmer, J. Electrochem. Soc., 129 (1982) 436.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Guillet, N., Pijolat, C. & Lalauze, R. Calorimetric Study of Interaction Between Oxygen and β-Al2O3, β-Al2O3+Au and β-Al2O3+Pt. Journal of Thermal Analysis and Calorimetry 68, 15–23 (2002). https://doi.org/10.1023/A:1014908230899
Issue Date:
DOI: https://doi.org/10.1023/A:1014908230899