Abstract
A procedure is proposed for studying acid decomposition of solid materials with the use of ion-selective electrodes, with the experimental data recorded and processed with a personal computer. Variation of the H3O+, F-, and Ca2 + concentrations in reaction of fluorapatite concentrate with nitric, sulfuric, and orthophosphoric acids and also the effect of particle size on the rate of solid phase decomposition were studied.
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REFERENCES
Protsenko, A.V., Kosyakov, N.E., Poyarkova, I.F., and Sergienko, I.D., Abstracts of Papers, 6 Nauchno-tekhnicheskii seminar po fosforu (Fosfor Ukrainy—93) [6th Scientific and Technical Seminar on Phosphorus (Phosphorus of Ukraine393)], Lviv, 1993, p. 28.
Kostyanets, P.V. and Popov, V.M., Issledovanie protsessa azotnokislotnogo razlozheniya apatitovogo kontsentrata kovdorskogo mestorozhdeniya (Study of Nitric Acid Decomposition of Apatite Concentrate from Kovdor Deposit), Available from Ukr. NIITI, 1987, Dnepropetrovsk Khimiko-Tekhnol. Inst., no. 2725.
RF Patent 2 086 507.
Tishkina, N.S. and Kostyanets, R.V., Tekhnologicheskie issledovaniya protsessa azotnokislogo razlozheniya khibinskogo apatitovogo kontsentrata (Technological Studies of Nitric Acid Decomposition of Khibiny Apatite Concentrate), Available from Ukr. NIITI, 1987, Dnepropetrovsk Khimiko-Tekhnol. Inst., no. 2723.
Tishkina, N.S. and Kostyanets, R.V., Kinetika protsessa azotnokislogo razlozheniya khibinskogo apatitovogo kontsentrata (Kinetics of Nitric-Acid Decomposition of Khibiny Apatite Concentrate), Available from Ukr. NIITI, 1987, Dnepropetrovsk Khimiko-Tekhnol. Inst., no. 2721.
Bovykin, P.A., Tishkina, N.S., Kostyanets, R.V., and Savchuk, S.N., Khim. Tekhnol., Kiev, 1988, no. 3, pp. 43-47.
Tishkina, N.S., Parkhomenko, V.D., Kostyanets, R.V., and Mazurova, L.G., Khim. Tekhnol., Kiev, 1985, no. 1, pp. 29-31.
Tishkina, N.S., Kostyanets, R.V., and Bondik, I.G., Khim. Tekhnol., Kiev, 1990, no. 1, pp. 71-73.
Jambor, Y. and Beranek, Y., Chemicky pramysl., 1984, vol. 34/59, no. 6, pp. 289-292.
Demina, L.A., Krasnova, N.B., Yurishcheva, B.S., and Chupakhin, M.S., Ionometriya v neorganicheskom analize (Ionometry in Inorganic Analysis), Moscow: Khimiya, 1991.
Lakshminarayanaiah, N., Membrane Electrodes, New York: Academic, 1976.
Laboratornye i tekhnologicheskie issledovaniya mineral'nogo syr'ya: Obzor informatsii, Vyp. 1. Primenenie ionometrii v analize mineral'nogo syr'ya (Laboratory and Technological Studies of Mineral Raw Materials: Information Review, issue 1: Use of Ionometry in Analysis of Mineral Resources), 1995.
Dobrydnev, S.V., Beskov, V.S., Bogach, V.V., and Pochitalkina, I.A., Teor. Osn. Khim. Tekhnol., 2001, vol. 35, no. 3, pp. 310-315.
Vasil'ev, V.P., Termodinamicheskie svoistva rastvorov elektrolitov (Thermodynamic Properties of Electrolyte Solutions), Moscow: Vysshaya Shkola, 1982.
Ryabin, V.A., Ostroumov, M.A., and Svit, T.F., Termodinamicheskie svoistva veshchestv: Spravochnik (Thermodynamic Properties of Substances: Reference Book), Leningrad: Khimiya, 1977.
Lur'e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1979.
Dobrydnev, S.V., Bogach, V.V., Pochitalkina, I.A., et al., Chem. Industry (Beograd), 2000, vol. 54, no. 7-8, pp. 319-323
Pochitalkina, I.A., Bogach, V.V., Dobrydnev, S.V., and Beskov, V.S. Abstracts of Papers, “Khimicheskii analiz veshchestv i materialov” (All-Russia Conf. “Chemical Analysis of Substances and Materials”), Moscow, 2000, pp. 375-376.
Nikol'skii, B.P. and Materova, E.A., Ionoselektivnye elektrody (Ion-Selective Electrodes), Leningrad: Khimiya, 1980.
Caldin, E.F., Fast Reactions in Solution, Oxford: Blackwell, 1964.
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Dobrydnev, S.V., Pochitalkina, S.A., Bogach, V.V. et al. Ionometric Study of the Kinetics of Acid Decomposition of Fluorapatite. Russian Journal of Applied Chemistry 74, 1627–1630 (2001). https://doi.org/10.1023/A:1014884514255
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DOI: https://doi.org/10.1023/A:1014884514255