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Chemistry of oxomolybdenum(V) and (VI) complexes incorporating oxygen, nitrogen and/or sulfur donor atoms. Part 1. Synthesis and characterization of [Mo2O3L4] (LH = HSCH2CH2CO2H, HSCH2CO2Me or HSCH2CH2CO2Me) and [MoO2L′2] (L′H = HOC6H4NH2, HOCH2C6H4NH2, HOC6H4CHO or HOC10H8N)

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Abstract

Reactions of an acidified aqueous solution of Na2MoO4 · 2H2O with 3-mercaptopropionic acid, 2-mercaptomethylethanoate and 3-mercaptomethyl propanate yield blue oxo-bridged MoV complexes of the type [Mo2O3L4], whereas corresponding reactions with 2-aminophenol, 2-aminobenzyl alcohol, salicylaldehyde and 2-methyl-8-hydroxyquinoline, yield yellow dioxomolybdenum(VI) complexes, [MoO2L′2]. All these coloured solids are sparingly soluble, even in coordinating solvents. They have been characterized by elemental and spectroscopic analysis.

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Authors and Affiliations

  1. Department of Chemistry, University of Rajasthan, Jaipur, 302004, India

    Purnima Nag, Rakesh Bohra & Ram C. Mehrotra

  2. Department of Applied Chemistry, MDS University, Ajmer, 305001, India

    Raju Ratnani

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  1. Purnima Nag
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  2. Rakesh Bohra
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Nag, P., Bohra, R., Mehrotra, R.C. et al. Chemistry of oxomolybdenum(V) and (VI) complexes incorporating oxygen, nitrogen and/or sulfur donor atoms. Part 1. Synthesis and characterization of [Mo2O3L4] (LH = HSCH2CH2CO2H, HSCH2CO2Me or HSCH2CH2CO2Me) and [MoO2L′2] (L′H = HOC6H4NH2, HOCH2C6H4NH2, HOC6H4CHO or HOC10H8N). Transition Metal Chemistry 27, 321–325 (2002). https://doi.org/10.1023/A:1014845702933

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