Skip to main content
Log in

Deposition of Films Based on Americium Isotopes by Vapor-Phase Thermal Decomposition of β-Diketonates and Their Adducts with Neutral Ligands

  • Published:
Radiochemistry Aims and scope

Abstract

Deposition of 243Am-based films by vapor-phase thermal decomposition of the americium hexafluoroacetylacetonate adduct Am(HFA)3·2TBP was studied. Films containing from fractions of microgram to several tens of micrograms of 243Am are deposited on iron, stainless steel, aluminum, and copper supports in a forevacuum (∼10- 2 mm Hg) at 340-400°C. The highest yields of 243Am deposition (∼75-85%) were obtained on iron and steel supports. Americium is presumably deposited in the form of AmF3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Reformatskaya, I.A., Radiokhimiya, 1971, vol. 13, no. 1, pp. 89-94.

    Google Scholar 

  2. Gvozdev, B.A. and Chuburkov, Yu.T., Radiokhimiya, 1963, vol. 5, no. 6, pp. 712-715.

    Google Scholar 

  3. Korotkin, Yu.S., Radiokhimiya, 1974, vol. 16, no. 3, pp. 377-382.

    Google Scholar 

  4. Fialkov, Yu.A. and Grishchenko, V.F., Elektrovydelenie metallov iz nevodnykh rastvorov (Electrolytic Deposition of Metals from Nonaqueous Solutions), Kiev: Naukova Dumka, 1985, p. 2-8.

    Google Scholar 

  5. Davydov, A.V., Myasoedov, B.F., Travnikov, S.S., and Fedoseev, E.V., Radiokhimiya, 1978, vol. 20, no. 2, pp. 257-264.

    Google Scholar 

  6. Davydov, A.V., Travnikov, S.S., Fedoseev, E.V., et al., Radiokhimiya, 1980, vol. 22, no. 4, pp. 522-528.

    Google Scholar 

  7. Sidorenko, G.V. and Suglobov, D.N., Radiokhimiya, 1982, vol. 24, no. 6, pp. 768-781.

    Google Scholar 

  8. Leikina, E.V., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1984, vol. 26, no. 3, pp. 413-415.

    Google Scholar 

  9. Mishin, V.Ya., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1986, vol. 28, no. 3, pp. 293-300.

    Google Scholar 

  10. Mishin, V.Ya., Solov'ev, S.M., Chinenov, P.M., et al., Radiokhimiya, 1985, vol. 27, no. 3, pp. 354-361.

    Google Scholar 

  11. Suglobov, D.N., Sidorenko, G.V., and Legin, E.K., Letuchie organicheskie i kompleksnye soedineniya f-elementov (Volatile Organic Derivatives and Coordination Compounds of f Elements), Moscow: Energoatomizdat, 1987.

    Google Scholar 

  12. Travnikov, S.S., Fedoseev, E.V., Davydov, A.V., and Myasoedov, B.F., in Teoreticheskaya i prikladnaya khimiya ?-diketonatov metallov (Theoretical and Applied Chemistry of Metal ?-Diketonates), Moscow: Nauka, 1985, pp. 220-223.

    Google Scholar 

  13. Travnikov, S.S., Fedoseev, E.V., Davydov, A.V., and Myasoedov, B.F., in Teoreticheskaya i prikladnaya khimiya ?-diketonatov metallov (Theoretical and Applied Chemistry of Metal ?-Diketonates), Moscow: Nauka, 1985, pp. 224-228.

    Google Scholar 

  14. Fedoseev, E.V., Ivanova, L.A., Travnikov, S.S., et al., Radiokhimiya, 1983, vol. 25, no. 3, pp. 361-366.

    Google Scholar 

  15. Sidorenko, G.V., Cand. Sci. (Chem.) Dissertation, Leningrad: Radium Inst., 1983.

    Google Scholar 

  16. Danilin, L.D., Dubok, E.V., Kartushin, V.D., et al., Radiokhimiya, 1987, vol. 29, no. 6, pp. 700-703.

    Google Scholar 

  17. Danilin, L.D. and Pilipenko, N.V., RF Patent 2081206, Publ. June 10, 1997, Byull. Izobret., 1997, no. 16.

  18. Gavrishchuk, E.M., Dzyubenko, N.G., and Martynenko, L.I., in Teoreticheskaya i prikladnaya khimiya ?-diketonatov metallov (Theoretical and Applied Chemistry of Metal ?-Diketonates), Moscow: Nauka, 1985, pp. 75-85.

    Google Scholar 

  19. Khomenko, V.S., Lozinskii, M.O., Fialkov, Yu.A., and Rasshinina, T.A., in Teoreticheskaya i prikladnaya khimiya ?-diketonatov metallov (Theoretical and Applied Chemistry of Metal ?-Diketonates), Moscow: Nauka, 1985, pp. 86-98.

    Google Scholar 

  20. Adamov, V.M., Belyaev, B.N., Berezinskii, S.O., et al., Preprint of the Radium Inst., Moscow, 1985, no. RI-185.

  21. Shannon, J.S. and Swan, J.W., Chem. Commun., 1965, no. 1, p. 33.

  22. Das, M. and Livingston, S.E., Aust. J. Chem., 1975, vol. 28, no. 7, pp. 1513-1516.

    Google Scholar 

  23. Gorshkov, N.I., Suglobov, D.N., and Sidorenko, G.V., Radiokhimiya, 1995, vol. 37, no. 3, pp. 196-200.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Danilin, L.D., Pilipenko, N.P., Maksimov, M.Y. et al. Deposition of Films Based on Americium Isotopes by Vapor-Phase Thermal Decomposition of β-Diketonates and Their Adducts with Neutral Ligands. Radiochemistry 44, 9–12 (2002). https://doi.org/10.1023/A:1014810814680

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1014810814680

Keywords

Navigation