Abstract
Deposition of 243Am-based films by vapor-phase thermal decomposition of the americium hexafluoroacetylacetonate adduct Am(HFA)3·2TBP was studied. Films containing from fractions of microgram to several tens of micrograms of 243Am are deposited on iron, stainless steel, aluminum, and copper supports in a forevacuum (∼10- 2 mm Hg) at 340-400°C. The highest yields of 243Am deposition (∼75-85%) were obtained on iron and steel supports. Americium is presumably deposited in the form of AmF3.
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REFERENCES
Reformatskaya, I.A., Radiokhimiya, 1971, vol. 13, no. 1, pp. 89-94.
Gvozdev, B.A. and Chuburkov, Yu.T., Radiokhimiya, 1963, vol. 5, no. 6, pp. 712-715.
Korotkin, Yu.S., Radiokhimiya, 1974, vol. 16, no. 3, pp. 377-382.
Fialkov, Yu.A. and Grishchenko, V.F., Elektrovydelenie metallov iz nevodnykh rastvorov (Electrolytic Deposition of Metals from Nonaqueous Solutions), Kiev: Naukova Dumka, 1985, p. 2-8.
Davydov, A.V., Myasoedov, B.F., Travnikov, S.S., and Fedoseev, E.V., Radiokhimiya, 1978, vol. 20, no. 2, pp. 257-264.
Davydov, A.V., Travnikov, S.S., Fedoseev, E.V., et al., Radiokhimiya, 1980, vol. 22, no. 4, pp. 522-528.
Sidorenko, G.V. and Suglobov, D.N., Radiokhimiya, 1982, vol. 24, no. 6, pp. 768-781.
Leikina, E.V., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1984, vol. 26, no. 3, pp. 413-415.
Mishin, V.Ya., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1986, vol. 28, no. 3, pp. 293-300.
Mishin, V.Ya., Solov'ev, S.M., Chinenov, P.M., et al., Radiokhimiya, 1985, vol. 27, no. 3, pp. 354-361.
Suglobov, D.N., Sidorenko, G.V., and Legin, E.K., Letuchie organicheskie i kompleksnye soedineniya f-elementov (Volatile Organic Derivatives and Coordination Compounds of f Elements), Moscow: Energoatomizdat, 1987.
Travnikov, S.S., Fedoseev, E.V., Davydov, A.V., and Myasoedov, B.F., in Teoreticheskaya i prikladnaya khimiya ?-diketonatov metallov (Theoretical and Applied Chemistry of Metal ?-Diketonates), Moscow: Nauka, 1985, pp. 220-223.
Travnikov, S.S., Fedoseev, E.V., Davydov, A.V., and Myasoedov, B.F., in Teoreticheskaya i prikladnaya khimiya ?-diketonatov metallov (Theoretical and Applied Chemistry of Metal ?-Diketonates), Moscow: Nauka, 1985, pp. 224-228.
Fedoseev, E.V., Ivanova, L.A., Travnikov, S.S., et al., Radiokhimiya, 1983, vol. 25, no. 3, pp. 361-366.
Sidorenko, G.V., Cand. Sci. (Chem.) Dissertation, Leningrad: Radium Inst., 1983.
Danilin, L.D., Dubok, E.V., Kartushin, V.D., et al., Radiokhimiya, 1987, vol. 29, no. 6, pp. 700-703.
Danilin, L.D. and Pilipenko, N.V., RF Patent 2081206, Publ. June 10, 1997, Byull. Izobret., 1997, no. 16.
Gavrishchuk, E.M., Dzyubenko, N.G., and Martynenko, L.I., in Teoreticheskaya i prikladnaya khimiya ?-diketonatov metallov (Theoretical and Applied Chemistry of Metal ?-Diketonates), Moscow: Nauka, 1985, pp. 75-85.
Khomenko, V.S., Lozinskii, M.O., Fialkov, Yu.A., and Rasshinina, T.A., in Teoreticheskaya i prikladnaya khimiya ?-diketonatov metallov (Theoretical and Applied Chemistry of Metal ?-Diketonates), Moscow: Nauka, 1985, pp. 86-98.
Adamov, V.M., Belyaev, B.N., Berezinskii, S.O., et al., Preprint of the Radium Inst., Moscow, 1985, no. RI-185.
Shannon, J.S. and Swan, J.W., Chem. Commun., 1965, no. 1, p. 33.
Das, M. and Livingston, S.E., Aust. J. Chem., 1975, vol. 28, no. 7, pp. 1513-1516.
Gorshkov, N.I., Suglobov, D.N., and Sidorenko, G.V., Radiokhimiya, 1995, vol. 37, no. 3, pp. 196-200.
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Danilin, L.D., Pilipenko, N.P., Maksimov, M.Y. et al. Deposition of Films Based on Americium Isotopes by Vapor-Phase Thermal Decomposition of β-Diketonates and Their Adducts with Neutral Ligands. Radiochemistry 44, 9–12 (2002). https://doi.org/10.1023/A:1014810814680
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DOI: https://doi.org/10.1023/A:1014810814680