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Cocrystallization of Radioiodine Compounds from the Gas Phase

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Abstract

The study of the behavior of 137Cs131I in the presence of MCl (M = NH4 +, K+, Ag+, and Cu+) in the water vapor-gas phase showed that CsI aerosols are localized in the MCl matrix owing to both agglomeration cocrystallization [137Cs131I-MCl systems (M = K+, Ag+, NH4 +)] and agglomeration capture [137Cs131I-CuCl system]. The main advantage of the first process is formation of crystalline globules encapsulating radioiodine in their bulk, which prevents transformation of radioiodine into elemental iodine and methyl iodide.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Moscow, Russia

    S. A. Kulyukhin, N. B. Mikheev, A. N. Kamenskaya, I. A. Rumer & V. L. Novichenko

  2. Chemical Faculty, Moscow State University, Moscow, Russia

    I. V. Melikhov

Authors
  1. S. A. Kulyukhin
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  2. N. B. Mikheev
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  3. A. N. Kamenskaya
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  4. I. V. Melikhov
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  5. I. A. Rumer
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  6. V. L. Novichenko
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Kulyukhin, S.A., Mikheev, N.B., Kamenskaya, A.N. et al. Cocrystallization of Radioiodine Compounds from the Gas Phase. Radiochemistry 43, 580–585 (2001). https://doi.org/10.1023/A:1014807924733

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  • DOI: https://doi.org/10.1023/A:1014807924733

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