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Mechanism of Electroreduction of Peroxodiphosphate Anions

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Abstract

The kinetic regularities of peroxodiphosphate anion reduction on dropping mercury and 40% thallium amalgam electrodes are studied. The reaction rate is found to increase with an increase in the supporting electrolyte and peroxodiphosphate anion concentrations, with the adsorption of inorganic cations on the electrode, and when the electrode exhibits a more negative zero-charge potential. The data obtained are analyzed within the Frumkin theory of slow discharge.

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Authors and Affiliations

  1. Moscow State University, Vorob'evy gory, Moscow, 119899, Russia

    N. V. Fedorovich & G. N. Botukhova

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  1. N. V. Fedorovich
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  2. G. N. Botukhova
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Fedorovich, N.V., Botukhova, G.N. Mechanism of Electroreduction of Peroxodiphosphate Anions. Russian Journal of Electrochemistry 38, 270–273 (2002). https://doi.org/10.1023/A:1014782707141

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