Abstract
Methylation of the coordinated heterocyclic thioamide ligand with dimethyl sulfate is studied. When boiled in dimethyl sulfate, bis(benzimidazole-2-N-phenylcarbothioamidato)copper(II) forms copper(II) complexes containing N-phenylbenzimidazole-2-(S-methylcarboisothioamide). The mechanism of this process is considered, and the reaction products are isolated and identified.
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Ranskii, A.P., Panasyuk, A.G. Direct Methylation of Bis(benzimidazole-2-N-phenylcarbothioamidato)copper(II). Russian Journal of Coordination Chemistry 28, 217–221 (2002). https://doi.org/10.1023/A:1014732204028
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DOI: https://doi.org/10.1023/A:1014732204028