Abstract
In this work, the thermal stability of organosilicon coatings, polyamide-6 powders and polyamide-6 clay nanocomposite powders coated with organosilicon are studied. The coatings were obtained from polymerization of 1.1.3.3-tetramethyldisiloxane (TMDS) monomer doped with oxygen using a cold remote nitrogen plasma (CRNP) process. A fluidized bed reactor using CRNP assisted polymerization was used to coat the polymer powders. The effect of oxygen addition to TMDS on the thermal stability was investigated. Oxygen addition to TMDS promotes the formation of more thermally stable coated polymers. In the case of the polyamide-6 clay nanocomposite, the Limiting Oxygen Index values were much improved. This shows that the deposits are effective fire retardant coatings.
Similar content being viewed by others
References
G. L. NELSON, in Proceedings of the American Chemical Society Symposium, Fire and Polymers II, edited by G. L. Nelson (American Chemical Society, Washington, DC, 1995) p. 1.
M. LEWIN, in “Fire Retardancy of Polymers, The Use of Intumescence,” edited by M. Le Bras, G. Camino, S. Bourbigot and R. Delobel (The Royal Society of Chemistry, Cambridge, 1998) p. 3.
J. TROITZSCH (ed.), in “International Plastics Flammability Handbook,” 2nd edn. (Hanser Publishers, Munich, 1990) p. 43.
J. BROSSAS, in “Techniques de l'Ingénieur,” edited by J. Debaene and B. L. Isra (Schiltigheim, 1998) AM 3 237 p. 1.
P. SUPIOT, F. CALLEBERT, O. DESSAUX and P. GOUDMAND, Plasma Chem. and Plasma Proc. 13 (1993) 539.
F. CALLEBERT, P. SUPIOT, K. ASFARDJANI, O. DESSAUX, P. GOUDMAND, P. DHAMELINCOURT and J. LAUREYNS, J. Appl. Polym. Sci. 52 (1994) 1595.
C. JAMA, thesis no 1554, Lille, France, 1995.
C. JAMA, K. ASFARDJANI, O. DESSAUX and P. GOUDMAND, J. Appl. Polym. Sci. 64 (1997) 699.
O. DESSAUX, P. GOUDMAND and C. JAMA, Surf. Coatings Technology 100/101 (1998) 34.
F. CALLEBERT, C. DUPRET, O. DESSAUX and P. GOUDMAND, Intern. Pat. Application,WO 92/03591 (1992).
F. CALLEBERT, P. SUPIOT, O. DESSAUX and P. GOUDMAND, PCT/FR94/00149 (1994).
L. CABURET, K. ASFARDJANI, O. DESSAUX, P. GOUDMAND and C. JAMA, FR 95/05333 (1995).
S. BOURBIGOT, C. JAMA, M. LE BRAS, R. DELOBEL, O. DESSAUX and P. GOUDMAND, Polym. Deg. and Stab. 66 (1999) 153.
C. JAMA, A. QUÉDÉ, M. LE BRAS, R. DELOBEL, O. DESSAUX, P. GOUDMAND, S. BOURBIGOT, J. W. GILMAN and T. KASHIWAGI, in Division of Polymeric Materials: Science and Engineering (96), American Chemical Society, 220th National Meeting, Washington, DC, August 20–24, 2000.
C. JAMA, G. BRETON, B. MUTEL, O. DESSAUX and P. GOUDMAND, in Proceedings of the 14th International Symposium on Plasma Chemistry, Prague, Republic Tcheck, 1999, p. 1287.
H. P. BROÏDA and M. W. CHAPMAN, An. Chem. 30 (1950) 2049.
C. DUPRET, P. SUPIOT, O. DESSAUX and P. GOUDMAND, Rev. Sci. Instrum. 65 (1994) 3439.
ASTM Standard D2863/77 (American Society for Testing and Materials, Philadelphia, PA, 1977).
D. R. ANDERSON (ed.), in “Infrared, Raman and Ultra-violet Spectroscopy, Analysis of Silicone,”(Wiley Interscience, NewYork, 1974).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Quédé, A., Cardoso, J., Le Bras, M. et al. Thermal stability and flammability studies of coated polymer powders using a plasma fluidized bed process. Journal of Materials Science 37, 1395–1399 (2002). https://doi.org/10.1023/A:1014576730732
Issue Date:
DOI: https://doi.org/10.1023/A:1014576730732