Skip to main content
SpringerLink
Log in

The nature of Pr-ZrSiO4 yellow ceramic pigment

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Pr-ZrSiO4 yellow ceramic pigment is believed to be a solid solution of Pr4+ with the zircon lattice, but studies are poor and scarce. The aim of this paper is the synthesis of Pr-ZrSiO4 yellow pigment in the presence of NaF by several non-conventional methods and to investigate the nature of the pigment. Results indicate that the formation of Pr-ZrSiO4 yellow pigment must be explained by two simultaneous mechanisms: formation of a solid solution of Pr in a ZrSiO4 network and an occlusion mechanism.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. EPPLER, Ceramic Bulletin 56 (1977) 213.

    Google Scholar 

  2. E. KATO and H. TAKASHIMA, Rep. Gov't. Res. Inst. Ceram. Kyoto 4 (1956) 147.

    Google Scholar 

  3. C. A. SEABRIGHT, US Patent 2,992,123, July 11, 1961.

  4. C. A. SEABRIGHT and H. C. DRAKER, Amer. Ceram. Soc. Bull. 40 (1961) 1.

    Google Scholar 

  5. F. T. BOOTH and G. N. PEEL, Trans. Brit. Ceram. Soc. 58 (1959) 532.

    Google Scholar 

  6. V. I. MATKOVITCH and P. M. CORBETT, J. Amer. Ceram. Soc. 44 (1961) 128.

    Google Scholar 

  7. K. SHAW, Ceramics 207 (1966) 22.

    Google Scholar 

  8. E. H. RAY, T. D. CARNAHAN and R. M. SULLIVAN, Ceramic Bull. 40 (1961) 13.

    Google Scholar 

  9. BATCHELOR, Meeting of the Pottery Section, Brit. Ceram. Soc., York, 3rd April, 1974.

  10. R. A. EPPLER, J. Amer. Ceram. Soc. 53 (1970) 8.

    Google Scholar 

  11. Idem., Ind. Eng. Chem. Prod. Res. Dev. 10 (1971) 352.

  12. J. A. HEDVALL, “Solid State Chemistry, Whence, Where and Whiter” (Elsevier, Amsterdam, 1967).

    Google Scholar 

  13. H. SCHMALRIZED, H. Angew. Chem. Int. Ed. Engl. 2 (1963) 251.

    Google Scholar 

  14. G. MONROS, J. CARDA, M. A. TENA, P. ESCRIBANO, M. SALES and J. ALARCÓN, J. Europ. Ceram. Soc. 11 (1993) 77.

    Google Scholar 

  15. A. C. AIREY and W. ROBERTS, Ceram. Eng. Sci. Proc. 8 (1987) 1168.

    Google Scholar 

  16. D. R. EPPLER, R. A. EPPLER and CHI-HANG-LI, ibid. 13 (1992) 109.

    Google Scholar 

  17. M. OCAÑA, A. CABALLERO, A. R. GONZÁLEZ-ELÍPE, P. TARTAJ and C. J. SERNA, J. Sol. State Chemistry 139 (1998) 412.

    Google Scholar 

  18. M. C. GRAÑANA, J. B. VICENT, M. LLUSAR, M. A. TENA and Y. G. MONRÓS, Bol. Soc. Cer. Vidr 39(2) (2000) 237.

    Google Scholar 

  19. POWCAL-LSQC Programmes, Ptt. of Chemistry, Abberdeen University (UK).

  20. CIE, Recommendations on Uniform Color Spaces, Color Difference Wquations, Psychometrics Color Terms, Suplement n°2 of CIE Pub., n°15(E1-1.31), Bureau Central de la CIE, Paris, 1978.

  21. R. C. GARVIE, R. H. NAHHICK and R. T. PASCOE, Nature 258 (1975) 703.

    Google Scholar 

  22. M. NOGAMI, J. Non-Cryst Solids 69 (1985) 415.

    Google Scholar 

  23. G MONROS, J. CARDA, M. A. TENA, P. ESCRIBANO and J. ALARCÓN, J. Mater. Sci. 27 (1992) 351.

    Google Scholar 

  24. G. DE, A. LICCIULLI and M. NACUCCHI, J. Non-Crystalline Solids 201 (1996) 153.

    Google Scholar 

  25. K. WEI, D. P. MACHEWIRTH, J. WENZEL, E. SNITZER and G. H. SIGEL JR., ibid. 182 (1995) 257.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic and Organic Chemistry, Jaume I University, Castellón, Spain

    J. A. Badenes, J. B. Vicent, M. Llusar, M. A. Tena & G. Monr

Authors
  1. J. A. Badenes
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. B. Vicent
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Llusar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. A. Tena
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. Monr
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Badenes, J.A., Vicent, J.B., Llusar, M. et al. The nature of Pr-ZrSiO4 yellow ceramic pigment. Journal of Materials Science 37, 1413–1420 (2002). https://doi.org/10.1023/A:1014537000690

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1014537000690

Keywords

Search

Navigation