Abstract
The formal kinetics of noncomplementary redox reactions in the coordination sphere of polynuclear complexes is considered. The kinetic descriptions of these processes and noncluster reactions differ substantially. The conditions were revealed under which the intracluster multielectron transformations of the substrate imitate the polymolecular reaction of consumption of one-electron reactants. The number of one-electron reactants in the coordination sphere of the reactive cluster is equal to the first derivative of the phase trajectory of the process with respect to the conversion at the very beginning of the reaction.
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Dzhabiev, T.S. Catalysis of noncomplementary reactions by transition metals clusters. Kinetic description. Russian Chemical Bulletin 50, 1833–1838 (2001). https://doi.org/10.1023/A:1014330028985
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DOI: https://doi.org/10.1023/A:1014330028985