Abstract
The formal kinetics of noncomplementary redox reactions in the coordination sphere of polynuclear complexes is considered. The kinetic descriptions of these processes and noncluster reactions differ substantially. The conditions were revealed under which the intracluster multielectron transformations of the substrate imitate the polymolecular reaction of consumption of one-electron reactants. The number of one-electron reactants in the coordination sphere of the reactive cluster is equal to the first derivative of the phase trajectory of the process with respect to the conversion at the very beginning of the reaction.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
E. T. Denisov, Kinetika gomogennykh khimicheskikh reaktsii [Kinetics of Homogeneous Chemical Reactions], Vysshaya Shkola, Moscow, 1988, 146 (in Russian).
N. N. Ovchinnikov and N. M. Shikhanova, Fotosintez [Photosynthesis], Prosveshchenie, Moscow, 1972, 158 pp. (in Russian).
A. E. Shilov, Metal Complexes in Biomimetic Chemical Reactions, Boca Raton, CRC Press, New York, 1997, 300 p.
R. Breslow, Chem. Soc. Rev., 1972, 1, 553.
A. E. Shilov, Cattech., 1999, 3, 72.
P. A. Shaffer, J. Am. Chem. Soc., 1933, 56, 2169.
S. N. Zelenin and M. L. Khidekel', Usp. Khim., 1970, 39, 209 [Russ. Chem. Rev., 1970, 39 (Engl. Transl.)].
N. N. Semenov, A. E. Shilov, and G. I. Likhtenshtein, Dokl. Akad. Nauk SSSR, 1975, 221, 1374 [Dokl. Chem., 1975 (Engl. Transl.)].
T. S. Dzhabiev, Kinet. Katal., 1998, 39, 487 [Kinet. Catal., 1998, 39 (Engl. Transl.)].
M. Spiro and A. Ravno, J. Chem. Soc., 1965, 78.
G. McLendon, in Energy Resources through Photochemistry and Catalysis, Ed. M. Graetzel, Acad. Press, New York-London, 1983, 114.
L. S. Pontryagin, Obyknovennye differentsial'nye uravneniya [Standard Differential Equations], Nauka, Gl. Red. Fiz.-Mat. Lit., Moscow, 1970, 103 (in Russian).
T. S. Dzhabiev, Kinet. Katal., 2001, 42, 512 [Kinet. Catal., 2001, 42 (Engl. Transl.)].
J. H. Baxendale and C. F. Wells, Trans. Faraday Soc., 1957, 53, 800.
C. Bull, E. C. Niederhoffer, T. Yoshida, and J. A. Fee, J. Am. Chem. Soc., 1991, 113, 4069.
T. C. Brunold, D. R. Gamelin, T. L. Stemmler, S. K. Mandal, W. H. Armstrong, J. E. Penner-Hahn, and E. I. Solomon, J. Am. Chem. Soc., 1998, 120, 8724.
J. Van't Hoff, Izbrannye trudy po khimii [Selected Works in Chemistry], Nauka, Moscow, 1984, 25 (Russ. Transl.).
G. M. Panchenkov and V. P. Lebedev, Khimicheskaya kinetika i kataliz [Chemical Kinetics and Catalysis], Khimiya, Moscow, 1974, 18 (in Russian).
E. S. Venttsel' and L. A. Ovcharov, Teoriya veroyatnostei i ee inzhenernye prilozheniya [Probability Theory and Its Engineering Applications], Nauka, Gl. Red. Fiz.-Mat. Lit., Moscow, 1988, 131 (in Russian).
T. S. Dzhabiev, S. A. Mironova, and A. E. Shilov, Kinet. Katal., 1999, 40, 844 [Kinet. Catal., 1999, 40 (Engl. Transl.)].
A. S. Davydov, Solitony v bioenergetike [Solitons in Bioenergetics], 1986, 124 (in Russian).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dzhabiev, T.S. Catalysis of noncomplementary reactions by transition metals clusters. Kinetic description. Russian Chemical Bulletin 50, 1833–1838 (2001). https://doi.org/10.1023/A:1014330028985
Issue Date:
DOI: https://doi.org/10.1023/A:1014330028985