Abstract
CO oxidation on a surface composed of two types of patches was simulated by the Monte Carlo method. Each patch has kinetic properties close to those of Pt(100) and Rh(100). The reaction rate was shown to increase significantly at the interface, involving COads on platinum and Oads on rhodium, under particular conditions.
Similar content being viewed by others
REFERENCES
W.C. Corner, J.L. Falconer: Chem.Rev., 95, 759 (1995).
B. Delmon, G.F. Froment: Catal.Rev.-Sci.Eng., 38, 69 (1996).
S.J. Teichner: Stud. Surf. Sci. Catal., Elsevier, 77, 27 (1993).
A.K. Tripathi, N.M. Cupta: J. Catal., 153, 208 (1995).
S.D. Gardner, G.B. Hoflund, B.T. Upchurch, D.R. Schryer, E.J. Kielen, J. Schryer: J. Catal., 129, 114 (1991).
Y.J. Mergler, J. Hoebink, B.E. Nieuwenhuys: J. Catal., 167, 305 (1997).
A.V. Kalinkin, V.I. Savchenko, A.V. Pashis: Catal. Lett., 59, 115 (1999).
S.H. Oh, J.E. Carpenter: J. Catal., 98, 178 (1986).
B.J. Brosilow, E. Gulari, R.M. Ziff.: J. Chem. Phys., 98, 674 (1993).
R.K. Herz, A. Badlani, D.R. Schryer, B.T. Upchurch: J. Catal., 141, 219 (1993).
V.I. Savchenko, N.I. Efremova: React. Kinet. Catal. Lett., 57, 49 (1996).
V.P. Zhdanov, B. Kasemo: Phys. Rev. Lett., 81, 2482 (1998).
V.P. Zhdanov, B. Kasemo: Surf. Sci. Rep., 39, 25 (2000).
R. Imbihl, A.E. Reynolds, D. Kalleta: Phys.Rev. Lett., 67, 275 (1991).
V.I. Savchenko: React.Kinet.catal.Lett., 55, 143 (1995).
M.A. Barteau, E.I. Ko, R.J. Madix: Surf. Sci., 102, 99 (1981).
A. Hopkinson, X.C. Guo, J.M. Bradley, D.A. King: J. Chem. Phys., 73, 5862 (1993).
C.T. Campbell, J.M. White: J. Catal., 54, 289 (1978).
W.M. Daniel, Y. Kim, H.C. Peebles, J.M. White: Surf. Sci., 111, 189 (1981).
A.N. Salanov, V.N. Bibin: Surf. Sci., 441, 399 (1999).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Efremova, N., Kalinkin, A. Modelling the Oxidation of CO at the Interface of Heterophase Metal Catalysts. Reaction Kinetics and Catalysis Letters 73, 373–379 (2001). https://doi.org/10.1023/A:1014144331162
Issue Date:
DOI: https://doi.org/10.1023/A:1014144331162