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Direct Partial Oxidation (dpo) of Methane to Higher Hydrocarbons by Modified h-Zsm5 Catalyst

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Abstract

The oxidation of methane has been studied in a flow system as a function of the chemical composition of zeolite catalyst using nitrous oxide as oxidant. It is concluded that methanol is a primary oxidation product which may undergo further oxidation to formaldehyde and to carbon oxides. However, it may also undergo conversion over the acidic catalyst to higher hydrocarbons. Reaction with nitrous oxide resulted in the production of carbon oxides, methanol, formaldehyde, C2 - C4 , C5 - C7 nonaromatics, and aromatics. The effect of Fe2 O3 and Al2 O3 , with or without, over HZSM5 on products was studied.

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Authors and Affiliations

  1. Research Institute of Petroleum Industry of National Iranian Oil Company, P.O.Box 18745-4163, Tehran, Iran

    Mohammad Behrooz & Ali Nakhaei Pour

  2. Department of Chemistry, Shahid Beheshti University, P.O.Box 19395-4716, Tehran, Iran

    Mohammad Hassan Peyrovi

Authors
  1. Mohammad Behrooz
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  2. Mohammad Hassan Peyrovi
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  3. Ali Nakhaei Pour
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Behrooz, M., Peyrovi, M.H. & Nakhaei Pour, A. Direct Partial Oxidation (dpo) of Methane to Higher Hydrocarbons by Modified h-Zsm5 Catalyst. Reaction Kinetics and Catalysis Letters 73, 127–133 (2001). https://doi.org/10.1023/A:1013993309356

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  • DOI: https://doi.org/10.1023/A:1013993309356

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