Abstract
Investigation on the nature of an initial mass loss observed for Mn(II)pyrrolidinedithiocarbamate complex is described. No evidences of decomposition are observed in infrared or mass spectra, elemental analysis and scanning electron microscopy of the residue at the end of the first thermal event, when compared with the same data for the original complex. Partial sublimation is assigned as the physical event after several experiments. The results are comparable with the findings for other complexes of the first transition series with pirrolidinedithiocarbamate.
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Couto, A.B., Bernal, C., Chierice, G.O. et al. Initial Mass Loss in Anhydrous Manganese(II) Pyrrolidinedithiocarbamate. Decomposition or sublimation. Journal of Thermal Analysis and Calorimetry 67, 433–437 (2002). https://doi.org/10.1023/A:1013972410469
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DOI: https://doi.org/10.1023/A:1013972410469