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Kinetic Analysis of the Thermal Decomposition of Dialkyldithiocarbamates Chelates of Indium(III)

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Abstract

The kinetics of thermal decomposition of solid In(S2CNR2)3 complexes, (R=CH3, C2H5, n-C3H7,i-C3H7, n-C4H9 and i-C4H9), has been studied using isothermal and non-isothermal thermogravimetry. Superimposed TG/DTG/DSC curves show that thermal decomposition reactions occur in the liquid phase, except for the In(S2CNMe2)3 and In(S2CNPri 2)3 compounds.

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Authors and Affiliations

  1. Departamento de Química, CCEN, Universidade Federal da Paraíba, 58059-900, cJoão Pessoa, Paraíba, Brazil

    A. G. Souza, M. M. Oliveira, I. M. G. Santos, M. M. Conceição & L. M. Nunes

  2. Departamento de Química, Universidade Federal de Minas Gerais, 31.270-901, Belo Horizonte, Minas Gerais, Brazil

    J. C. Machado

Authors
  1. A. G. Souza
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  2. M. M. Oliveira
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  3. I. M. G. Santos
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  4. M. M. Conceição
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  5. L. M. Nunes
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  6. J. C. Machado
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Correspondence to A. G. Souza.

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Souza, A.G., Oliveira, M.M., Santos, I.M.G. et al. Kinetic Analysis of the Thermal Decomposition of Dialkyldithiocarbamates Chelates of Indium(III). Journal of Thermal Analysis and Calorimetry 67, 359–363 (2002). https://doi.org/10.1023/A:1013971031425

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  • DOI: https://doi.org/10.1023/A:1013971031425

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