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Kinetic Laws Governing Thermal Decomposition of Perchlorate Nickel Organometallic Complexes Under Changes of the Ligand Nature

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Journal of Engineering Physics and Thermophysics Aims and scope

As a result of the interaction of nickel perchlorate with ethylenediamine, imidazole, and semicarbazide, complex compounds Ni(En)3(ClO4)2, Ni(Im)6(ClO4)2, and Ni(SC)3(ClO4)2 have been obtained, the structure and composition of which were confirmed by elemental analysis and by the method of the infrared spectroscopy of frustrated total internal reflection. The kinetics of the thermal decomposition of synthesized compounds in an inert medium was studied within the framework of the traditional method of thermal analysis in a helium atmosphere at a rate of the heating of samples of 5°C/min and under conditions of their high-speed heating (>100°C/min) with simultaneous determination of the composition of gaseous products of thermal decomposition of the material.

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Authors and Affiliations

  1. V. V. Voevodskii Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 Institutskaya Str., Novosibirsk, 630090, Russia

    A. G. Shmakov & A. A. Paletskii

  2. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 Academician Lavrentiev Ave., Novosibirsk, 630090, Russia

    O. V. Komova, S. A. Mukha, K. A. Dmitruk & O. V. Netskina

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  1. A. G. Shmakov
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  2. A. A. Paletskii
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  3. O. V. Komova
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  4. S. A. Mukha
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  6. O. V. Netskina
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Correspondence to A. G. Shmakov.

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Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 95, No. 7, pp. 1780–1793, November–December 2022.

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Shmakov, A.G., Paletskii, A.A., Komova, O.V. et al. Kinetic Laws Governing Thermal Decomposition of Perchlorate Nickel Organometallic Complexes Under Changes of the Ligand Nature. J Eng Phys Thermophy 95, 1732–1745 (2022). https://doi.org/10.1007/s10891-022-02644-2

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  • DOI: https://doi.org/10.1007/s10891-022-02644-2

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