Abstract
In Part I of this series results on the formation of Pd-organic amine adducts, their polymerization, and the catalytic behavior of the catalyst formed were reported [1]. In the present paper results of IR and N2 adsorption measurements are discussed. This includes the interactions of organic amines and Pd. Conclusions were drawn on the physical structure of the catalyst. Under the applied reaction conditions the Pd-containing polymers were formed to a certain extent, but in all cases a non-negligible part of the Pd-amine adduct remains unchanged.
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Petró, J., László, K., Kiss, J.T. et al. Palladium as Catalyst in a Polycondensed Matrix, Part ii. Reaction Kinetics and Catalysis Letters 73, 187–197 (2001). https://doi.org/10.1023/A:1013918114807
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DOI: https://doi.org/10.1023/A:1013918114807