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Polymer-modified supported palladium catalysts for the hydrogenation of acetylene compounds

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Abstract

Palladium catalysts supported on zinc oxide modified with polyethylene glycol or pectin were synthesized and investigated in the hydrogenation of acetylene compounds. It was established that the polymercontaining catalysts reduce acetylene hyrbons to olefins with high activity, selectivity, and stability. The composition and structure of the obtained composites were studied by elemental analysis, transmission electron microscopy, and XPS spectroscopy. It was found that the nanosized particles of palladium uniformly immobilized on the surface of zinc oxide were formed in the course of the synthesis of a supported polymer/oxide complex.

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Authors and Affiliations

  1. Sokol’skii Institute of Organic Catalysis and Electrochemistry, Academy of Sciences of Kazakhstan, Almaty, 050010, Kazakhstan

    A. K. Zharmagambetova, K. S. Seitkalieva, E. T. Talgatov, A. S. Auezkhanova & A. D. Pomogailo

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    G. I. Dzhardimalieva

Authors
  1. A. K. Zharmagambetova
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  2. K. S. Seitkalieva
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  3. E. T. Talgatov
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  4. A. S. Auezkhanova
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  5. G. I. Dzhardimalieva
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  6. A. D. Pomogailo
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Corresponding authors

Correspondence to A. K. Zharmagambetova or G. I. Dzhardimalieva.

Additional information

Original Russian Text © A.K. Zharmagambetova, K.S. Seitkalieva, E.T. Talgatov, A.S. Auezkhanova, G.I. Dzhardimalieva, A.D. Pomogailo, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 3, pp. 362–369.

Communication no. 77 from the series Reactivity of Metal-Containing Monomers. For communication no. 76, see Izv. Akad. Nauk, Ser. Khim., 2016, no. 1, p. 139 [Russ. Chem. Bull., 2016, vol. 65, no. 1].

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Zharmagambetova, A.K., Seitkalieva, K.S., Talgatov, E.T. et al. Polymer-modified supported palladium catalysts for the hydrogenation of acetylene compounds. Kinet Catal 57, 360–367 (2016). https://doi.org/10.1134/S0023158416030174

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  • DOI: https://doi.org/10.1134/S0023158416030174

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