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Synthesis and structural characterization of [Ni(Me2NCH2CH2CH2N=CHC6H4O)2]

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Abstract

The synthesis, properties, and X-ray crystal structure of a Ni(II) complex of the tridentate Schiff base ligand Me2NCH2CH2CH2N=CHC6H4OH(LH) are described. The complex crystallizes in the monoclinic space group P21/c, with a = 10.180(2), b = 15.169(3), c = 15.293(4) Å, β = 106.69(2)°, and Z = 4. The Ni atom shows a distorted fac-octahedral geometry, with the two Ni—N(Me2) bonds being significantly longer than the two Ni—N(imino) bonds, 2.284(9), 2.310(9) vs. 2.051(2), 2.055(2) Å.

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Calcutta West Bengal, 700 032, India

    Chirantan R. Choudhury, Subrata K. Dey, Nijhuma Mondal & Samiran Mitra

  2. Department of Chemistry, Cardiff University, P.O. Box 912, Park Place, Cardiff, CF10 3TB, United Kingdom

    S. Ozra Ghodsi Mahalli & Khalifa Mohammad Abdul Malik

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  1. Chirantan R. Choudhury
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  2. Subrata K. Dey
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  3. Nijhuma Mondal
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  4. Samiran Mitra
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  5. S. Ozra Ghodsi Mahalli
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  6. Khalifa Mohammad Abdul Malik
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Choudhury, C.R., Dey, S.K., Mondal, N. et al. Synthesis and structural characterization of [Ni(Me2NCH2CH2CH2N=CHC6H4O)2]. Journal of Chemical Crystallography 31, 57–62 (2001). https://doi.org/10.1023/A:1013782703964

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