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X-ray crystal structure of a macrocyclic tetraamine nitrito nickel(II) complex

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Abstract

The compound [Ni(L)(η2-NO2)]ClO4 (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized and structurally characterized. It crystallizes in the monoclinic system, space group P21/c with a = 26.899(5), b = 8.476(2), c = 23.633(5) Å, β = 115.12(13)°, V = 4878.6(17) Å3, and Z = 4. Each nickel(II) ion has a six-coordinated bicapped square-pyramidal geometry with four secondary amines of the macrocycle and two oxygen atoms of the bidentate nitrito group. Electronic spectra and effective magnetic moment of the complex also exhibit a high-spin six-coordinated geometry.

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References

  1. Cotton, F.A.; Edwards,W.T. Acta Crystallogr., Sect. B 1968, 24, 474.

    Google Scholar 

  2. Shvelashvili, A.E.; Porai-Koshits, M.A. Koord. Khim. 1975, 1, 467.

    Google Scholar 

  3. Nardelli, M.; Pelizzi, G. Inorg. Chim. Acta 1980, 38, 15.

    Google Scholar 

  4. Drew, M.G.B.; Goodgame, D.M.L.; Hitchman, M.A.; Rogers, D. Chem. Commun. 1965, 477.

  5. Meyer, A.; Gleizes, A.; Girerd, J.J.; Verdaguer, M.; Kahn, O. Inorg. Chem. 1982, 21, 1729.

    Google Scholar 

  6. Hay, R.W.; Lawrance, G.A.; Curtis, N.F. J. Chem. Soc., Perkin Trans. 1 1975, 591.

  7. Sheldrick, G.M. Acta Crystallogr., Sect. A 1990, 46, 467.

    Google Scholar 

  8. Sheldrick, G.M. SHELXL97, Program for the Refinement of Crystal Structures; University of Göttingen: Germany, 1997.

    Google Scholar 

  9. Johnson, C.K. ORTEP, A Fortran Thermal Ellipsoid Plot Program; Technical Report ORNL-5138, Oak Ridge National Laboratory: Oak Ridge, 1976.

    Google Scholar 

  10. Mochizuki, K.; Kondo, T. Inorg. Chem. 1995, 34, 6241.

    Google Scholar 

  11. Oshio, H. Inorg. Chem. 1993, 32, 4123.

    Google Scholar 

  12. Freeman, G.M.; Barefield, E.K.; Derveer, D.G.V. Inorg. Chem. 1984, 23, 3092.

    Google Scholar 

  13. Barefield, E.K.; Freeman G.M.; Derveer, D.G.V. J. Chem. Soc., Chem. Commun. 1983, 1385.

  14. Martin, L.Y.; Sperati, C.R.; Busch, D.H. J. Am. Chem. Soc. 1977, 99, 2968.

    Google Scholar 

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Authors and Affiliations

  1. Department of Cultural Heritage Conservation Science, Kongju National University, Kongju, 314-701, South Korea

    Ki-Young Choi

  2. Department of Physics, Kongju National University, Kongju, 314-701, South Korea

    Moon-Won Kim & Ji-Wook Ryu

  3. Department of Chemistry, Kongju National University, Kongju, 314-701, South Korea

    Suk Nam Choi & Byung Bin Park

  4. Department of Geoenvironmental Science, Kongju National University, Kongju, 314-701, South Korea

    Mancheol Suh

  5. Department of Physics, Chungnam National University, Taejon, 305-764, South Korea

    Il-Hwan Suh

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  1. Ki-Young Choi
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  2. Moon-Won Kim
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  3. Ji-Wook Ryu
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  4. Suk Nam Choi
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  5. Byung Bin Park
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  6. Mancheol Suh
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  7. Il-Hwan Suh
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Choi, KY., Kim, MW., Ryu, JW. et al. X-ray crystal structure of a macrocyclic tetraamine nitrito nickel(II) complex. Journal of Chemical Crystallography 31, 81–86 (2001). https://doi.org/10.1023/A:1013743022619

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  • DOI: https://doi.org/10.1023/A:1013743022619

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