Abstract
4-Vinylbenzyl phenyl ether, 4-phenylbenzyl phenyl ether, 1- and 2-naphthylmethyl phenyl ethers react with sodium thiophenolate under photochemical stimulation with replacement of the phenoxy group. The composition of reaction products and relation of reactivity to the structure of substrates is consistent with anion-radical mechanism. The corresponding methoxy and cyano derivatives do not undergo the reaction.
Similar content being viewed by others
REFERENCES
Rossi, R.A. and Bunnett, J.F., J. Org. Chem., 1973, vol. 38, no. 7, pp. 1407–1410.
Bunnett, J.F. and Gloor, B.F., J. Org. Chem., 1973, vol. 38, no. 24, pp. 4156–4163.
Dneprovskii, A.S. and Tuchkin, A.I., Zh. Org. Khim., 1994, vol. 30, no. 3, pp. 404–410.
Dneprovskii, A.S. and Tuchkin, A.I., Zh. Org. Khim., 1997, vol. 33, no. 11, pp. 1684–1690.
Dneprovskii, A.S. and Tuchkin, A.I., Zh. Org. Khim., 1997, vol. 33, no. 11, pp. 1691–1695.
Bunnett, J.F. and Creary, X., J. Org. Chem., 1974, vol. 39, no. 21, pp. 317333174.
Rossi, R.A., de Rossi, R.H., and Lopez, A.F., J. Org. Chem., 1976, vol. 41, no. 21, pp. 3371–3373.
Zervas, L. and Dilaris, I., J. Am. Chem. Soc., 1955, vol. 77, no. 20, pp. 5354–5357.
Organikum. Organisch-Chemisches Grundpraktikum, Berlin: VEB Deutscher Verlag der Wissenschaften, 1976.
Shorigin, P., Ber., 1926, vol. 59, pp. 2502–2509.
Shorigin, P., Ber., 1926, vol. 59, pp. 2509–2514.
Kutyrev, G.A., Kapura, A.A., Sadykova, L.A., Nikanorov, V.A., Cherkasov, R.A., and Pudovik, A.N., Zh. Obshch. Khim., 1987, vol. 57, no. 1, pp. 56–63.
Wittig, G. and Leo, M., Ber., 1930, vol. 63, pp. 943–949.
Gomberg, M. and Pernert, J.C., J. Am. Chem. Soc., 1926, vol. 48, no. 5, pp. 1372–1384.
Kraft, F. and Bourgeous, E., Ber., 1890, vol. 23, pp. 3045–3049.
Truce, W.E. and Hampton, D.C., J. Org. Chem., 1963, vol. 28, no. 9, pp. 2276–2279.
Paquette, L.A., Klobucar, W.D., and Snow, R.A., Synth. Commun., 1973, vol. 6, no. 8, pp. 575–581.
Markees, D.G., Helv. Chim. Acta, 1973, vol. 56, no. 4, pp. 1382–1384.
Lapkin, I.I. and Lapkina, O.M., Zh. Obshch. Khim., 1951, vol. 21, no. 1, pp. 108–117.
Blank, O., Ber., 1896, vol. 29, pp. 2373–2375.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dneprovskii, A.S., Fedosov, I.V. Fragmentation of Anion Radicals with Elimination of Aryloxy Groups. Russian Journal of Organic Chemistry 37, 1438–1443 (2001). https://doi.org/10.1023/A:1013456112725
Issue Date:
DOI: https://doi.org/10.1023/A:1013456112725