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Isothermal Vapor–Liquid Equilibria for the Ternary System 2-Propanol + Tetrahydrofuran + 1-Chlorobutane at 25°C

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Abstract

Isothermal vapor–liquid equilibria (VLE) for mixtures containing 2-propanol + tetrahydrofuran + 1-chlorobutane have been measured using a modified version of a Boublik–Benson still at 25°C. A test of thermodynamic consistency, like the McDermott–Ellis method was applied to the activity coefficients. Excess molar Gibbs free energies were calculated over the entire range composition. Different expressions existing in the literature were used to predict activity coefficients.

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REFERENCES

  1. J. A. Salas and M. Katz, J. Solution Chem. 24, 357 (1995).

    Google Scholar 

  2. J. A. Salas, E. L. Arancibia, and M. Katz, Fluid Phase Equilibr. 152, 255 (1998).

    Google Scholar 

  3. I. L. Acevedo, G. C. Pedrosa, M. Katz, L. L. Mussari, and M. A. Postigo, Acta Equifase 99, COBEQ. 259.

  4. J. Birós, A. Zivny, and J. Pouchly, J. Chim. Phys. 72, 255 (1998).

    Google Scholar 

  5. S. C. Sharma, M. Tomar, and J. Singh, J. Solution Chem. 22, 391 (1993).

    Google Scholar 

  6. T. Boublik and G. C. Benson, Can. J. Chem. 47, 539 (1969).

    Google Scholar 

  7. J. A. Riddick, W. S. Bunger, and T. Sakano, Organic Solvents, 4th edn. (Wiley New York, 1986).

    Google Scholar 

  8. J. Polak, S. Murakami, G. C. Benson, and H. F. P. Plug, Can. J. Chem. 48, 3782 (1970).

    Google Scholar 

  9. J. G. Hayden and J. P. O'Connell, Ind. Eng. Chem. Process Design Develop. 14, 209 (1975).

    Google Scholar 

  10. C. McDermott and S. R. N. Ellis, Chem. Eng. Sci. 20, 293 (1965).

    Google Scholar 

  11. A. Tamir and J. Wisniak, J. Chem. Eng. Data 32, 291 (1987).

    Google Scholar 

  12. D. W. Marquardt, J. Soc. Appl. Math. 2, 431 (1963).

    Google Scholar 

  13. N. Radojkovic, A. Tasic, D. Grozdanic, B. Djordevic, and M. M. Malic, J. Chem. Thermodyn. 9, 349 (1977).

    Google Scholar 

  14. K. Jacob and K. Fitzner, Thermochim. Acta 18, 197 (1977).

    Google Scholar 

  15. F. Kohler, Monatsch. Chem. 91, 738 (1960).

    Google Scholar 

  16. I. Cibulka, Collect. Czech. Chem. Commun. 47, 1414 (1982).

    Google Scholar 

  17. J. M. Prausnitz, Molecular Thermodynamics of Fluid Phase Equilibria (Prentice Hall, Upper Saddle River, NJ, 1969).

    Google Scholar 

  18. A. Fredenslund, J. Gmehling, and P. Rasmussen, Vapor–Liquid Equilibria using UNIFAC (Elsevier, New York, 1977).

    Google Scholar 

  19. J. Gmehling, P. Rasmussen, and A. Fredenslund, Ind. Eng. Chem. Process Design Develop. 21, 118 (1982).

    Google Scholar 

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Acevedo, I.L., Pedrosa, G.C., Arancibia, E.L. et al. Isothermal Vapor–Liquid Equilibria for the Ternary System 2-Propanol + Tetrahydrofuran + 1-Chlorobutane at 25°C. Journal of Solution Chemistry 30, 1029–1037 (2001). https://doi.org/10.1023/A:1013355411329

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  • DOI: https://doi.org/10.1023/A:1013355411329

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