Abstract
Isothermal vapor–liquid equilibria (VLE) for mixtures containing 2-propanol + tetrahydrofuran + 1-chlorobutane have been measured using a modified version of a Boublik–Benson still at 25°C. A test of thermodynamic consistency, like the McDermott–Ellis method was applied to the activity coefficients. Excess molar Gibbs free energies were calculated over the entire range composition. Different expressions existing in the literature were used to predict activity coefficients.
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REFERENCES
J. A. Salas and M. Katz, J. Solution Chem. 24, 357 (1995).
J. A. Salas, E. L. Arancibia, and M. Katz, Fluid Phase Equilibr. 152, 255 (1998).
I. L. Acevedo, G. C. Pedrosa, M. Katz, L. L. Mussari, and M. A. Postigo, Acta Equifase 99, COBEQ. 259.
J. Birós, A. Zivny, and J. Pouchly, J. Chim. Phys. 72, 255 (1998).
S. C. Sharma, M. Tomar, and J. Singh, J. Solution Chem. 22, 391 (1993).
T. Boublik and G. C. Benson, Can. J. Chem. 47, 539 (1969).
J. A. Riddick, W. S. Bunger, and T. Sakano, Organic Solvents, 4th edn. (Wiley New York, 1986).
J. Polak, S. Murakami, G. C. Benson, and H. F. P. Plug, Can. J. Chem. 48, 3782 (1970).
J. G. Hayden and J. P. O'Connell, Ind. Eng. Chem. Process Design Develop. 14, 209 (1975).
C. McDermott and S. R. N. Ellis, Chem. Eng. Sci. 20, 293 (1965).
A. Tamir and J. Wisniak, J. Chem. Eng. Data 32, 291 (1987).
D. W. Marquardt, J. Soc. Appl. Math. 2, 431 (1963).
N. Radojkovic, A. Tasic, D. Grozdanic, B. Djordevic, and M. M. Malic, J. Chem. Thermodyn. 9, 349 (1977).
K. Jacob and K. Fitzner, Thermochim. Acta 18, 197 (1977).
F. Kohler, Monatsch. Chem. 91, 738 (1960).
I. Cibulka, Collect. Czech. Chem. Commun. 47, 1414 (1982).
J. M. Prausnitz, Molecular Thermodynamics of Fluid Phase Equilibria (Prentice Hall, Upper Saddle River, NJ, 1969).
A. Fredenslund, J. Gmehling, and P. Rasmussen, Vapor–Liquid Equilibria using UNIFAC (Elsevier, New York, 1977).
J. Gmehling, P. Rasmussen, and A. Fredenslund, Ind. Eng. Chem. Process Design Develop. 21, 118 (1982).
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Acevedo, I.L., Pedrosa, G.C., Arancibia, E.L. et al. Isothermal Vapor–Liquid Equilibria for the Ternary System 2-Propanol + Tetrahydrofuran + 1-Chlorobutane at 25°C. Journal of Solution Chemistry 30, 1029–1037 (2001). https://doi.org/10.1023/A:1013355411329
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DOI: https://doi.org/10.1023/A:1013355411329