Abstract
Titanium-substituted large pore SSZ-42 zeolite was synthesized for the first time using the corresponding borosilicate as starting material. Substitution of boron by titanium took place via either high temperature treatment with TiCl4 vapor or by treatment with Ti(OiPr)4 in dry toluene at 120°C. Both deboronated and boron-containing samples were found to be suitable for post-synthesis incorporation of titanium in the zeolite framework. The obtained materials were characterized by FTIR, UV-visible and XPS. Titanium-modified SSZ-42 was found to be active for phenol hydroxylation and cyclohexene epoxidation.
Similar content being viewed by others
References
M. Taramasso, G. Perego and B. Notari, US Patent 4 410 501 (1983).
G. Perego, G. Bellussi, G. Corno, M. Taramasso, F. Buonomo and A. Esposito, Stud. Surf. Sci. Catal. 28 (1986) 129.
B. Kraushaar and J.H.C. van Hooff, Catal. Lett. 1 (1988) 81.
J.M. Fraille, J.J. Garcia, J.A. Mayoral, L.C. de Menorval and F. Paradis, J. Chem. Soc. Chem. Commun. (1995) 539.
A. Corma, M.T. Navarro and J. Pérez-Pariente, J. Chem. Soc. Chem. Commun. (1994) 147.
A. Sayari, K.M. Reddy and I. Moudrakowski, Stud. Surf. Sci. Catal. 98 (1995) 19.
P.T. Tanev, M. Chibwe and T.J. Pinnavaia, Nature 368 (1994) 321.
J.S. Reddy and A. Sayari, Appl. Catal. A 128 (1995) 231.
K. Kulawik, G. Schulz-Ekloff, J. Rathouský, A. Zukal and J. Had, Collect. Czech. Chem. Commun. 60 (1995) 451.
A. Carati, C. Flego, E. Previde Massara, R. Millini, L. Carluccio, W.O. Parker Jr. and G. Bellussi, Micropor. Mesopor. Mater. 30 (1999) 137.
M.E. Davis, Micropor. Mesopor. Mater. 21 (1998) 173.
J.S. Reddy, R. Kumar and P. Ratnasamy, Appl. Catal. 58 (1990) L1.
C.B. Dartt, C.B. Khouw, H.X. Li and M.E. Davis, Micropor. Mater. 2 (1994) 425.
J.S. Reddy and A. Sayari, Stud. Surf. Sci. Catal. 94 (1995) 309.
C.B. Dartt and M.E. Davis, Appl. Catal. A 143 (1996) 53.
M.J. Díaz-Cabañas, L.A. Villaescusa and M.A. Camblor, Chem. Commun. (2000) 761.
C.Y. Chen, L.W. Finger, R.C. Medrud, P.A. Crozier, I.Y. Chan, T.V. Harris and S.I. Zones, Chem. Commun. (1997) 1775.
C. Chen, L.W. Finger, R.C. Medrud, C.L. Kibby, P.A. Crozier, I.Y. Chan, T.V. Harris, L.W. Beck and S.I. Zones, Chem. Eur. J. 4 (1998) 1312.
S.I. Zones, US Patent 5 770 175 (1998).
M.S. Rigutto, R. de Ruiter, J.P.M. Niederer and H. van Bekkum, Stud. Surf. Sci. Catal. 84 (1994) 2245.
R. De Ruiter, K. Pamin, A.P.M. Kentgens, J.C. Jansen and H. van Bekkum, Zeolites 13 (1993) 611.
A. Tuel, Micropor. Mesopor. Mater. 27 (1999) 151.
G. Horvath and K. Kawazoe, J. Chem. Eng. Jpn. 16 (1983) 470.
A. Esposito, M. Taramasso and C. Neri, US Patent 4 396 783 (1982).
C. Neri, A. Esposito, B. Anfossi and F. Buonomo, EP 100 119 (1984).
M.G. Clerici and P. Ingallina, J. Catal. 140 (1993) 1993.
A.V. Ramaswamy, S. Sivbasanker and P. Ratnaswamy, Micropor. Mater. 2 (1994) 451.
J.S. Reddy, P. Liu and A. Sayari, Appl. Catal. A 148 (1996) 7.
J.S. Reddy and A. Sayari, J. Chem. Soc. Chem. Commun. (1995) 23.
R. de Ruiter, A.P.M. Kentgens, J. Grootendorst, J.C. Jansen and H. van Bekkum, Zeolites 13 (1993) 128.
M.R. Boccuti, K.M. Rao, A. Zecchina, G. Leofanti and G. Petrini, Stud. Surf. Sci. Catal. 48 (1989) 133.
Z. Fu, D. Yin, Q. Li, L. Zhang and Y. Zhang, Micropor. Mesopor. Mater. 29 (1999) 351.
C.D. Wagner, W.M. Riggs, L.E. Davis, J.F. Moulder and G.E. Muilenberg, Handbook of X-Ray Photoelectron Spectra ( Perkin-Elmer, Eden Prairie, MN, 1979).
D. Wei, W. Chueh and G.L. Haller, Catal. Today 51 (1999) 501.
A. Corma, P. Esteve, A.Martinez and S. Valencia, J. Catal. 152 (1995) 18.
M. Besson, M.C. Bonnet, P. Gallezot, I. Tkatchenko and A. Tuel, Catal. Today 51 (1999) 547.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hamoudi, S., Larachi, F. & Sayari, A. Synthesis and Characterization of Titanium-Substituted Large Pore SSZ-42 Zeolite. Catalysis Letters 77, 227–231 (2001). https://doi.org/10.1023/A:1013266223722
Issue Date:
DOI: https://doi.org/10.1023/A:1013266223722