Skip to main content
Log in

Thorium(IV) sorption on ignited Sarcotragus muscarum, its kinetic and thermodynamic parameters

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The uptake of thorium from aqueous systems by ignited Sarcotragus muscarum(L. Schmidt, 1864), collected from Kusadasi Region at Southwest of Turkeyas an adsorbent has been investigated. The thorium(IV) uptake was studiedas a function of pH, ion concentration and temperature. At the determinedoptimum conditions, the sorption of thorium on ignited sponge follows a Langmuir-typeisotherm. We assumed that this phenomenon can be a sorption process. Kineticof thorium sorption was investigated at different time intervals at 25, 50and 70 °C. The reaction rate and diffusion constants were calculated forthese temperatures. The activation energy and .H° were found to be –19.04and –5.22 J/mol, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. T. Sakaguchi,A. Nakajima, J. Chem. Tech. Biotechnol., 40 (1987) 133.

    Google Scholar 

  2. T. Sakaguchi,T. Horikoshi,A. Nakajima, J. Ferment. Technol., 56 (1978) No. 6, 561.

    Google Scholar 

  3. T. Sakaguchi,T. Horikoshi,A. Nakajima, Agric. Biol. Chem., 45 (1989) No. 10, 2191.

    Google Scholar 

  4. T. I. Stocer,R. L. Usinger (Eds), Elements of Zoology, 2nd ed., 1961.

  5. M. E. Cinar,Z. Ergen, Ophelia, 48 (1998) No. 3, 167.

    Google Scholar 

  6. H. Onishi, Photometric Determination of Traces Metals, 4th ed., Part IIB, Wiley-Interscience, 1989.

  7. A. I. Vogel, Textbook of Quantitative Inorganic Analysis, Longmans, Green & Co. Ltd., London, 1975.

    Google Scholar 

  8. R. Chiarizia,E. P. Horwitz,S. D. Alexandratos, Solvent Extr. Ion Exch., 4 (1994).

  9. C. E. Harland, Ion Exchange: Theory and Practise, The Royal Society of Chemistry, UK, 1994.

    Google Scholar 

  10. D. Langmuir,J. S. Herman, Geochim. Cosmochim. Acta, 44 (1980) 1753.

    Google Scholar 

  11. F. A. Cotton,G. Wilkinson, Adv. Inorg. Chem., 3rd ed., Interscience Publishers, John Wiley & Sons, 1972.

  12. K. D. Pennell,L. M. Abriola,W. J. Weber, Environ. Sci. Technol., 27 (1993) 2332.

    Google Scholar 

  13. W. J. Weber,P. M. McGinley,L. E. Katz, Environ. Sci. Technol., 26 (1992) 1955.

    Google Scholar 

  14. W. J. Weber,K. D. Pennell,T. J. Dekker,L. M. Abriola, in: Advanced in Groundwater Pollution Control and Remediation, M. Aral (Ed.), NATO-ASI, Kemer, Turkey, 1995.

    Google Scholar 

  15. R. F. Gould, Proc. Symp. on Sorption from Aqueous Solution, Sep. 14–15, 1967, Advances in Chemistry Series 79, American Chemical Society, Washington D.C., 1968.

    Google Scholar 

  16. S. Akyil,M. A. A. Aslani,S. (Ölmez) Aytas¸, J. Alloys Comp., 271/273 (1998) 769.

  17. S. Akyil,M. A. A. Aslani,S¸. Ölmez,M. Eral, J. Radioanal. Nucl. Chem., 213 (1996) 441.

    Google Scholar 

  18. S. A. Khan,R. Ur-Rehman,M. A. Khan, Waste Managem., 15 (1995) No. 4, 271.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Eral, M. Thorium(IV) sorption on ignited Sarcotragus muscarum, its kinetic and thermodynamic parameters. Journal of Radioanalytical and Nuclear Chemistry 250, 153–157 (2001). https://doi.org/10.1023/A:1013203618134

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1013203618134

Keywords

Navigation