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Palladium(II), Copper(II), Iron(III), and Vanadium(V) Complexes with Heteropolyanion PW9O9–34: 31P, 183W, 51V NMR and IR Spectroscopy Studies

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Abstract

The formation of Pd(II)-containing and mixed Pd(II),Cu(II), Pd(II),Fe(III), and Pd(II),V(V) complexes with heteropolyanion PW9O9– 34was studied using 31P, 183W, 51V NMR, visible UV and IR spectroscopy, and the differentiating dissolution methods. In an aqueous solution and at optimal pH (3.7), the monometallic complexes [Pd3(PW9O34)2]12–and [Pd3(PW9O34)2Pd n O x H y ]q–(n av= 3), the bimetallic complexes [Pd2Cu(PW9O34)2]12–, [Pd2Fe(PW9O34)2]11–, and [PdFe2(PW9O34)2]10–, and a mixture of the [Pd3(PW9O34)2Pd n O x H y ]q–(n av≈ 10) + [(VO)3(PW9O34)2]9–complexes are formed. The title complexes were isolated from solution as Cs+solid salts belonging to the same [M3(PW9O34)2] structural type.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, Novosibirsk, 630090, Russia

    L. G. Detusheva, L. I. Kuznetsova, M. A. Fedotov, V. A. Likholobov, L. S. Dovlitova, A. A. Vlasov & V. V. Malakhov

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  1. L. G. Detusheva
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  2. L. I. Kuznetsova
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  3. M. A. Fedotov
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  4. V. A. Likholobov
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  5. L. S. Dovlitova
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  6. A. A. Vlasov
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  7. V. V. Malakhov
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Detusheva, L.G., Kuznetsova, L.I., Fedotov, M.A. et al. Palladium(II), Copper(II), Iron(III), and Vanadium(V) Complexes with Heteropolyanion PW9O9–34: 31P, 183W, 51V NMR and IR Spectroscopy Studies. Russian Journal of Coordination Chemistry 27, 838–845 (2001). https://doi.org/10.1023/A:1013056927629

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