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Physical Chemistry of Lanthanide Uranophosphates and Uranoarsenates

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The heterogeneous equilibria LnCl3 (solution in H2O)-HP(As)UO6·4H2O (crystal) and HCl (solution in H2O)-Ln[P(As)UO6]3·nH2O (crystal), where Ln = La, Gd, Lu, were studied experimentally, and the standard Gibbs energiess of formation of the compounds Ln[P(As)UO6]3·nH2O (Ln = La, Gd, Lu) were calculated. For the compounds La(PUO6)3·14H2O and La(AsUO6)3·15H2O the isobaric heat capacities in the range 80-300 K were measured calorimetrically, the enthalpies of formation at 298.15 K were determined, and the absolute entropies, entropies of formation, and Gibbs energies of formation were calculated. The results obtained from data on heterogeneous equilibria were compared with those of direct calorimetric measurements.

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REFERENCES

  1. Olken, M.M., Verschoor, C.M., and Ellis, A.B., Inorg. Chem., 1986, vol. 25, pp. 80–82.

    Google Scholar 

  2. Pozas–Tormo, R., Moreno–Real, L., Martinez–Lara, M., and Bruque–Gamez, S., Inorg. Chem., 1987, vol. 26, pp. 1442–1445.

    Google Scholar 

  3. Dorhout, K.D., Sabel, D.M., and Ellis, A.B., J. Less–Common Met., 1989, vol. 156, pp. 439–449.

    Google Scholar 

  4. Chernorukov, N.G., Suleimanov, E.V., Barch, S.V., and Alekseev, E.V., Radiokhimiya, 2001, vol. 43, no. 1, pp. 9–15.

    Google Scholar 

  5. Chernorukov, N.G., Suleimanov, E.V., Barch, S.V., and Alekseev, E.V., Radiokhimiya, 2001, vol. 43, no. 3, pp. 209–215.

    Google Scholar 

  6. Karyakin, N.V., Chernorukov, N.G., Suleimanov, E.V., and Alimzhanov, M.I., Zh. Obshch. Khim., 1999, vol. 69, no. 5, pp. 724–727.

    Google Scholar 

  7. Lebedev, B.V. and Lityagov, V.Ya., in Termodinamika organicheskikh soedinenii: Mezhvuzovskii sbornik (Thermodynamics of Organic Compounds: Intercollegiate Coll.), Gor'kii, 1976, issue 5, pp. 89–97.

  8. Termicheskie konstanty veshchestv (Thermal Constants of Substances), Glushko, V.P., Ed., Moscow: Akad. Nauk SSSR, 1965–1981, issues I–X.

    Google Scholar 

  9. Kumok, V.N., Kuleshova, O.N., and Karabin, A.A., Proizvedeniya rastvorimosti (Solubility Products), Novosibirsk: Nauka, 1983.

    Google Scholar 

  10. Mochalov, L.A., Cand. Sci. (Chem.) Dissertation, Nizhni Novgorod: Lobachevskii State Univ., 1998.

    Google Scholar 

  11. Kelley, K.K., Parks, G.S., and Huffman, H.M., J. Phys. Chem., 1929, vol. 33, no. 12, pp. 1802–1807.

    Google Scholar 

  12. Parks, G.S. and Huffman, H.M., The Free Energies of Some Organic Compounds, New York: Chem. Catalog, 1932.

    Google Scholar 

  13. Karyakin, N.V., Chernorukov, N.G., Suleimanov, E.V., and Mochalov, L.A., Zh. Obshch. Khim., 1998, vol. 68, no. 3, pp. 372–374.

    Google Scholar 

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  1. Lobachevskii State University, Nizhni Novgorod, Russia

    N. G. Chernorukov, E. V. Suleimanov & S. V. Barch

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  1. N. G. Chernorukov
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  2. E. V. Suleimanov
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  3. S. V. Barch
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Chernorukov, N.G., Suleimanov, E.V. & Barch, S.V. Physical Chemistry of Lanthanide Uranophosphates and Uranoarsenates. Radiochemistry 43, 246–251 (2001). https://doi.org/10.1023/A:1012852323353

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  • DOI: https://doi.org/10.1023/A:1012852323353

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