Skip to main content
SpringerLink
Log in

Formation of Excited Uranyl in U(IV) Oxidation with Oxygen in Aqueous HClO4 Solutions: III. Effects of Deuteration of Solvents and Heterogeneous Decay of Radicals

  • Published:
Radiochemistry Aims and scope

Abstract

The surface of the glass introduced in the form of spheres with R = 1 mm into Teflon reactor affects both the kinetics of the liquid-phase chemiluminescent chain-radical oxidation of U(IV) with oxygen and the efficiency of conversion of the chemical reaction energy into the light energy. In the case of deuterated solutions, the reaction deceleration and the decrease in the chemiluminescence efficiency in the presence of the glass were less pronounced. A mechanism of the chemiluminescent reaction was considered which assigns an important role to heterogeneous decay of OH and HO2 (OD and DO2) radicals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Kazakov, V.P., Khemilyuminestsentsiya uranila, lantanoidov i d–elementov (Chemiluminescence of Uranyl, Lanthanides, and d Elements), Moscow: Nauka, 1980.

    Google Scholar 

  2. Lotnik, S.V., Khamidullina, L.A., and Kazakov, V.P., Radiokhimiya, 1993, vol. 35, no. 2, pp. 50–59.

    Google Scholar 

  3. Lotnik, S.V., Kazakov, V.P., and Tolstikov, G.A., Dokl. Akad. Nauk SSSR, 1985, vol. 284, no. 2, pp. 382–385.

    Google Scholar 

  4. Lotnik, S.V and Kazakov, V.P., Nizkotemperaturnaya khemilyuminestsentsiya (Low–Temperature Chemiluminescence), Moscow: Nauka, 1987.

    Google Scholar 

  5. Lotnik, S.V., Khamidullina, L.A., and Kazakov, V.P., Dokl. Ross. Akad. Nauk, 1999, vol. 366, no. 3, pp. 345–348.

    Google Scholar 

  6. Lotnik, S.V., Khamidullina, L.A., and Kazakov, V.P., Radiokhimiya, 2001, vol. 43, no. 1, pp. 48–52.

    Google Scholar 

  7. Lotnik, S.V., Khamidullina, L.A., and Kazakov, V.P., Radiokhimiya, 2001, vol. 43, no. 1, pp. 53–56.

    Google Scholar 

  8. Lotnik, S.V., Khamidullina, L.A., and Kazakov, V.P., Radiokhimiya, 1998, vol. 40, no. 3, pp. 203–207.

    Google Scholar 

  9. Khamidullina, L.A., Lotnik, S.V., and Kazakov, V.P., Radiokhimiya, 1998, vol. 40, no. 3, pp. 208–212.

    Google Scholar 

  10. Koltunov, V.S., Kinetika reaktsii aktinoidov (Kinetics of Actinide Reactions), Moscow: Atomizdat, 1974.

    Google Scholar 

  11. Rozenshtein, V.B., Gershenzon, Yu.M., Il'in, S.V., et al., Kinet. Katal., 1986, vol. 27, no. 5, pp. 536–542.

    Google Scholar 

  12. Gershenzon, Yu.M., Ivanov, A.V., Kucheryavyi, S.I., and Rozenshtein, V.B., Kinet. Katal., 1986, vol. 27, no. 5, pp. 1069–1074.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia

    S. V. Lotnik, L. A. Khamidullina & V. P. Kazakov

Authors
  1. S. V. Lotnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Khamidullina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. P. Kazakov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lotnik, S.V., Khamidullina, L.A. & Kazakov, V.P. Formation of Excited Uranyl in U(IV) Oxidation with Oxygen in Aqueous HClO4 Solutions: III. Effects of Deuteration of Solvents and Heterogeneous Decay of Radicals. Radiochemistry 43, 265–270 (2001). https://doi.org/10.1023/A:1012808508332

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1012808508332

Keywords

Search

Navigation