Abstract
The kinetics of electrodeposition of nickel-chromium alloys from chromium(III) sulfate electrolytes containing succinic and malonic acids was studied. The effect exerted by the electrolysis mode and the pH of the electrolyte on the composition and quality of the obtained coatings was investigated. The possibility of obtaining protective and decorative nickel-chromium coatings containing 20-55% chromium is established.
Similar content being viewed by others
REFERENCES
Prikladnaya elektrokhimiya (Applied Electrochemistry), Kudryavtsev, N. T., Ed., Moscow: Khimiya, 1975.
Bogoraz, L.Ya., Khromirovanie (Chromium Plating), Leningrad: Mashinostroenie, 1984.
Gal'vanicheskie pokrytiya v mashinostroenii: Spravochnik (Electroplating in Engineering: Reference Book), Shluger, M.F., Ed., Moscow: Mashinostroenie, 1985, vol. 1.
Falicheva, A.I., Zh. Vsesoyuzn. Khim. Obshch. im. D. I. Mendeleeva, 1964, vol. 9, no. 8, pp. 555-557.
USSR Inventor's Certificate, no. 1 177 398.
USSR Inventor's Certificate, no. 1 636 481.
Kudryavtsev, V.N. and Vinokurov, E.G., Abstracts of Papers, 15-i Mendeleevskii s''ezd po obshchei i prikladnoi khimii (15th Mendeleev Congress on General and Applied Chemistry), Minsk, Belarus, 1993, pp. 166-167.
Falicheva, A.I. and Burdykina, R.I., Gal'vanotekhn. Obrabotka Poverkhn., 1997, vol. 5, no. 1, pp. 15-19.
Remy, H., Lehrbuch der Anorganischen Chemie, vol. 2, Leipzig: Akademische Verlagsgesellschaft Geest and Portig K.-G., 1961.
Grinberg, A.A., Vvedenie v khimiyu kompleksnykh soedinenii, Leningrad: Goskhimizdat, 1951.
Lavrukhima, A.K. and Yukina, L.V., Analiticheskaya khimiya khroma (Analytical Chemistry of Chromium), Moscow: Nauka, 1979.
Falicheva, A.I., Elektrokhim., 1968, vol. 4, no. 7, pp. 856-858.
Falicheva, A.I., Shalimov, Yu.N., and Ionova, I.G., Zashch. Met., 1972, vol. 8, no. 4, pp. 499-503.
Shalimov, Yu.N., Falicheva, A.I., and Spiridonov, B.A., Zashch. Met., 1977, vol. 13, no. 15, pp. 623-625.
Elinek, T.V., Gal'vanotekhn. Obrabotka Poverkhn., 1997, vol. 5, no. 2, pp. 7-23.
Fedot'ev, N.P., Bibikov, N.N., Vyacheslavov, P.M., and Grilikhes, S.Ya., Elektroliticheskie splavy (Electrolytic Alloys), Moscow: Mashgiz, 1962.
Vyacheslavov, P.M., Elektroliticheskoe osazhdenie splavov (Electrodeposition of Alloys), Leningrad: Mashinostroenie, 1980.
Kudryavtsev, V.N. and Tsupak, T.E., Issledovaniya v oblasti fizicheskoi khimii, analiticheskoi khimii i elektrokhimii (Investigations in Physical Chemistry, Analytical Chemistry, and Electrochemistry), Moscow: Mendeleev Inst. Chem. Technol., 1963, no. 64, pp. 80-85.
Kudryavtsev, V.N. and Tsupak, T.E., Issledovaniya v oblasti fizicheskoi khimii, analiticheskoi khimii i elektrokhimii (Investigations in Physical Chemistry, Analytical Chemistry, and Electrochemistry), Moscow: Mendeleev Inst. Chem. Technol., 1963, no. 64, pp. 96-101.
Zvyagintseva, A.V., Falicheva, A.I., Spiridonov, B.A., and Shalimov. Yu.N., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1988, vol. 31, no. 12, pp. 91-95.
Falicheva, A.I., Matantsev, A.I., and Lavrinova, A.E., Zh. Prikl. Khim., 1964, vol. 37, no. 12, pp. 2600-2606.
Lur'e Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1979.
Shalimov, Yu.N., Spiridonov, B.A., Satarov, V.V., and Falicheva, A.I., Zashch. Met., 1986, vol. 22, no. 1, pp. 95-98.
Kublanovskii, V.S., Gorodyskii, A.V., Belinskii, L.N., and Glushchak, G.S., Kontsentratsionnye izmeneniya v prielektrodnykh sloyakh v protsesse elektroliza (Concentration Changes in Near-Electrode Layers in the Course of Electrolysis), Kiev: Naukova Dumka, 1978.
Zabotin, P.I. and Kozlovskii, M.T., Izv. Akad. Nauk Kazakh. SSR, Ser. Khim., 1956, issue 6, no. 10, pp. 64-68.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Spiridonov, B.A., Falicheva, A.I. Electrodeposition of Nickel-Chromium Coatings from Chromium(III) Sulfate Electrolytes . Russian Journal of Applied Chemistry 74, 214–218 (2001). https://doi.org/10.1023/A:1012761831491
Issue Date:
DOI: https://doi.org/10.1023/A:1012761831491