Abstract
Experimental results obtained in a study of the voltammetric response of an all-solid fluoride-selective electrode based on LaF3 (Eu2+ 0.8 mol %), LaF3 (Sr2+ 5 mol %) and CeF3 (Sr2+ 5 mol %) single crystals brought in contact with Ag, Bi, and Sn metal samples are presented. The method of cathodic inversion voltammetry was applied to study the reduction of La3+ and Ce3+-cations from the rigid sublattice of solid electrolytes, which determines the threshold of the electrochemical stability of a membrane. Anodic inversion voltammetry was used to investigate the characteristics of solid-phase generation of metal fluorides at the interface between the fluoride-selective electrode and metals.
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REFERENCES
Spravochnoe rukovodstvo po primeneniyu ionoselektivnykh elektrodov (Handbook of the Use of Ion-Selective Electrodes), Petrukhin, O.M., Ed., Moscow: Mir, 1986.
Turaeva, M.S., Pegova, I.A., Vasilevskii, V.L., and Grilikhes, M.S., Zh. Prikl. Khim., 1996, vol. 69, no. 8, pp. 1321-1331.
Turaeva, M.S., Pegova, I.A., Vasilevsky, V.L., and Grilikhes, M.S., Proc. 10th Eur. Conf. on Solid-State Transducers, Eurosensors-10, Leuven, Belgium, September 8 —11, 1996, pp. 191-195.
Turaeva, M.S., Lyalin, O.O., and Vasilevskii, V.L., Elektrokhimiya, 1992, vol. 28, no. 10, pp. 1505-1511.
Yamazoe, N., Hisamoto, J., and Miura, N., Sensors Actuators, 1987, vol. 11, no. 12, pp. 415-423.
Harke, S., Wiemhofer, H.-D., and Gopel, W., Sensors Actuators B, 1990, vol. 1, no. 1-6, pp. 188-194.
Turaeva, M.S., Pegova, I.A., and Vasilevskii, V.L., Elektrokhimiya, 1996, vol. 32, no. 4, pp. 491-497.
Turaeva, M.S., Elektrokhimiya, 1996, vol. 32, no. 4, pp. 498-502.
Lyalin, O.O., Turaeva, M.S., and Mogilevskii, B.M., Elektrokhimiya, 1977, vol. 13, no. 11, pp. 1716-1718.
Delahay, P., New Instrumental Methods in Electrochemistry; Theory, Instrumentation and Application to Analytical and Physical Chemistry, New York: Interscience, 1954.
Vydra, F., Štulik, K., and Julákova, E., Rozpouštécí Polarografic a Voltametrie, Praha: Nakladatelstvi technicke literatury, 1977.
Galus, Zb., Teoretyczue Podstawy Elektroanalisy Chemicznej, Warszawa: Panstwowe Wydawnictwo Naukowe, 1971.
Macdonald, D.D., Transient Techniques in Electrochemistry, New York: Plenum, 1981.
Calandra, A.J., de Tacconi, N.R., Pereiro, R., and Arvia, A.J., Electrochim. Acta, 1974, vol. 19, no. 12, pp. 901-905.
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Turaeva, M.S., Kot, S.A., Glumov, O.V. et al. Voltammetry with a Fluoride-Selective Electrode with Solid-Phase Reference System. Russian Journal of Applied Chemistry 74, 596–602 (2001). https://doi.org/10.1023/A:1012758515388
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DOI: https://doi.org/10.1023/A:1012758515388