Abstract
An analysis of the characteristics of operating devices and prototypes based on fluorine-conducting solid electrolytes allows for estimating the lower fluoride conductivity limits σ293 K that are sufficient for using these electrolytes in electrochemical devices operating at room temperature. The estimated σ293 K values for different electrochemical devices differ strongly: σ293 K > 10−3 S/cm for fluorine ion current sources and fluorine gas detection sensors and σ293 K > 10−5 S/cm for fluorine fluid sensors (ion-selective electrodes). The fluoride materials that are promising as solid electrolytes in fluorine-ion batteries and accumulators, fluorine-selective electrodes, and gas fluorine gas sensors operating at room temperature are listed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. A. Potanin, Zh. Vseross. Khim. O-va im. D. I. Mendeleeva XLV(5–6), 58 (2001).
A. A. Potanin, RF Patent No. RU2295178 (21 April, 2005).
C. Rongeat, M. Anji Reddy, R. Witter, and M. Fichtner, J. Phys. Chem. C 117, 4943 (2013).
M. Anji Reddy and M. Fichtner, J. Mater. Chem. 21, 17059 (2011).
D. Jakes, J. Kaplan, V. Trnovcova, and B. P. Sobolev, Abst. III Asian Conf. Solid State Ionics, Varanasi, 1992, p. 147.
I. V. Murin, O. V. Glumov, and D. B. Samusik, Zh. Prikl. Khim., No. 10, 2171 (1991).
A. N. Aleinichev, N. N. Aleinichev, N. N. Vershinin, and Yu. I. Malov, Proc. IX All-Union Symp. on Chemistry of Fluorides, Cherepovets, 3–6 July, 1990, p. 13.
B. P. Sobolev and N. I. Sorokin, Kristallografiya 52(5), 870 (2007).
B. P. Sobolev, N. I. Sorokin, E. A. Krivandina, and Z. I. Zhmurova, Crystallogr. Rep. 59(4), 550 (2014).
B. P. Sobolev and N. I. Sorokin, Crystallogr. Rep. 59(6), 807 (2014).
N. I. Sorokin and B. P. Sobolev, Phys. Solid State 50(3), 416 (2008).
N. I. Sorokin and M. W. Breiter, Solid State Ionics 99, 241 (1997).
A. Roos, F. C. M. van de Pol, R. Keim, and J. Schoonman, Solid State Ionics 13, 191 (1984).
N. I. Sorokin, I. I. Buchinskaya, and B. P. Sobolev, Zh. Neorg. Khim. 37(12), 2653 (1992).
N. I. Sorokin, P. P. Fedorov, and B. P. Sobolev, Inorg. Mater. 33(1), 1 (1997).
C. Lucat, G. Campet, J. Claverie, and J. Portier, Mater. Res. Bull. 11, 167 (1976).
J. M. Reau, S. Matar, S. Kasim, et al., Solid State Ionics 7, 165 (1982).
I. V. Murin, Doctoral Dissertation in Chemistry (Leningrad Gos. Univ., Leningrad, 1983).
S. Matar, J. M. Reau, C. Lucat, et al., Mater. Res. Bull. 15, 1295 (1980).
B. P. Sobolev, N. I. Sorokin, E. A. Krivandina, and Z. I. Zhmurova, Crystallogr. Rep. 60(1), 123 (2015).
M. W. Shafer, G. V. Chandrashekhar, and R. A. Figat, Solid State Ionics 5, 633 (1981).
A. Rhandour, J. M. Reau, S. Matar, et al., Mater. Res. Bull. 20, 1309 (1985).
M. S. Frant and J. W. Ross, Science 154(3756), 1553 (1966).
I. Ya. Gallai, K. E. Lisker, K. K. Rivkina, and A. L. Rusman, Proc. IV All-Union Symp. on Chemistry of Fluorides, Dushanbe, 29 September–3 October, 1975, p. 155.
N. I. Sorokin, M. V. Fominykh, E. A. Krivandina, et al., Proc. Int. Conf. “Glass and Solid Electrolytes”, St. Petersburg, 17–19 May, 1999, p. 27.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.I. Sorokin, B.P. Sobolev, 2015, published in Kristallografiya, 2015, Vol. 60, No. 3, pp. 431–434.
Rights and permissions
About this article
Cite this article
Sorokin, N.I., Sobolev, B.P. Conductivity limit of fluorine-conducting solid electrolytes for electrochemical devices operating at room temperature. Crystallogr. Rep. 60, 384–387 (2015). https://doi.org/10.1134/S1063774515030189
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063774515030189