Abstract
The mechanism of acetol formation in two-stage process of sulfuric acid cleavage of cumyl hydroperoxide was studied and confirmed by comparison with related reaction systems.
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REFERENCES
Messina, G., Lorezoni, L., Cappellazzo, O., and Gamba, A., Chim. Ind. (Milan), 1983, vol. 65, no. 1, pp. 10-17.
Pasterean, M., C. R. Acad. Sci. Paris, 1907, vol. 144, pp. 90-93.
USSR Patent 1 361 937.
Tsypysheva, L.G., Mishchenko, L.Ya., and Portnova, T.V., Zh. Anal. Khim., 1987, vol. 42, no. 2, pp. 347-351.
Antonovskii, V.L. and Terent'ev, V.A., in Uspekhi khimii organicheskikh perekisnykh soedinenii i autookisleniya (Advances in Chemistry of Organic Peroxides and Autooxidation), Moscow: Khimiya, 1969, pp. 442-450.
Dickey, F.H., Rust, F., and Vaughan, W.E., J. Am. Chem. Soc., 1949, vol. 71, pp. 1432-1434.
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Vasil'eva, I.I., Zakoshanskii, V.M., Koshelev, Y.N. et al. Pathways of Acetol Formation in the Course of Production of Phenol and Acetone by Cleavage of Cumyl Hydroperoxide. Russian Journal of Applied Chemistry 74, 111–113 (2001). https://doi.org/10.1023/A:1012712420588
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DOI: https://doi.org/10.1023/A:1012712420588