Abstract
Characterization of the local environment of metallic ions (Cu, Fe, Ti, Ni and Er) implanted in the ceramic matrix AlN have led us to conclude that the heat of formation (\Delta H) of the implanted ion nitride (I-N) is the parameter which has to be considered in order to predict the final system. When ΔHI-N is negative, bonds between the implanted ion and nitrogen atoms are formed, when ΔHI-N is positive, clusters of the implanted ion are formed. Moreover, we give some physical characteristics of the Cu and Ni clusters in the AlN matrix and show the differences between imbedded and deposited clusters of the same size.
Similar content being viewed by others
References
A. Traverse, P. Parent, J. Mimault, S. Hagège and J. Du, Nucl. Instr. Methods B 84 (1994) 204.
M. Borovski, A. Traverse and J. Mimault, Acta Physica Polonica A 86 (1994) 713.
M. Borowski, A. Traverse and J.P. Dallas, J. Mater. Res. 10 (1995) 3136.
M. Borowski, A. Traverse and J.P. Eymery, Nucl. Instr. Methods B 122 (1997) 247.
Smithells Metals Reference Book, 6th edn., ed. E. Brandes (Butterworth, 1983) Chapter 8.
J. Chaumont, F. Lalu, M. Salomé and A.M. Lamoise, Nucl. Instr. Methods 189 (1981) 193.
H. Bernas, J. Chaumont, E. Cottereau, R. Meunier, A. Traverse, C. Clerc, O. Kaitasov, F. Lalu, D. Le Du, G. Moroy and M. Salomé, Nucl. Instr. Methods B 62 (1992) 416.
J. Mimault, J.J. Faix, T. Girardeau, M. Jaouen and G. Tourillon, Meas. Sci. Technol. 5 (1994) 482.
A. Michalowicz, Logiciels pour la Chimie, Vol. 102 (Société Française de Chimie, Paris, 1991).
M. Borowski, in: Proc. of the 9th Int. Conf. on X-ray Absorption Fine Structure, Grenoble, France, August 1996.
G. Apai, J.F. Hamilton, J. Stohr and A. Thomson, Phys. Rev. Lett. 43 (1979) 165.
M. de Crescenzi, M. Diociaiuti, L. Lozzi, P. Picozzi, S. Santucci, C. Battistoni and G. Mattogno, Surf. Sci. 178 (1986) 282.
A. Balerna, E. Bernieri, P. Picozzi, A. Reale, S. Santucci, E. Burattini and S. Mobilio, Phys. Rev. B 31 (1985) 5058.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Traverse, A. Metallic clusters in the AlN ceramic. Hyperfine Interactions 110, 159–164 (1997). https://doi.org/10.1023/A:1012642509118
Issue Date:
DOI: https://doi.org/10.1023/A:1012642509118