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CEMS of nitride coatings in agressive environments

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Abstract

The corrosion properties of single layered TiN and CrN films have been compared to bi-layered and multi-layered Ti/TiN films. XPS has showed that in humid SO2 atmosphere the best corrosion properties have been achieved by a multi-layered Ti/TiN coating. Cyclic voltammetry in acetate buffer has been applied to measure the porousity and corrosion resistance of coatings. The best results have been achieved by multi-layered Ti/TiN and CrN films. Conversion electron Mössbauer spectroscopy has been used to study the changes in the interface Fe/TiN during thermal treatment in UHV. It has been shown that the amount of iron nitrides in the interface increases with increasing temperature.

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Authors and Affiliations

  1. J. Stefan Institute, University of Ljubljana, P.O. Box 3000, SLO-1001, Ljubljana, Slovenia

    D. Hanžel

  2. Instituto de Quimica-Fisica “Rocasolano”, CSIC, Serrano 119, 28006, Madrid, Spain

    A.C. Agudelo, J.R. Gancedo & J.F. Marco

  3. Department of Physical Chemistry, Eötvös University, P.O.B. 32, H-1518, Budapest, Hungary

    M. Lakatos-Varsanyi

Authors
  1. D. Hanžel
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  2. A.C. Agudelo
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  3. J.R. Gancedo
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  4. M. Lakatos-Varsanyi
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  5. J.F. Marco
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Hanžel, D., Agudelo, A., Gancedo, J. et al. CEMS of nitride coatings in agressive environments. Hyperfine Interactions 111, 93–100 (1998). https://doi.org/10.1023/A:1012633129107

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