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Reactions of [Fluoro(methylsulfonyloxy)iodo]benzene: II. Reaction of [Fluoro(sulfonyloxy)iodo]benzene with Acyclic Olefins

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Abstract

Reactions of [fluoro(sulfonyloxy)iodo]benzene with 1-hexene and 1-heptene smoothly yield the corresponding 1,2-disulfonates. Reaction of [fluoro(sulfonyloxy)iodo]benzenes with methyl methacrylate results in formation of isomeric α-fluoro-β-sulfonyloxy products. A possible reaction mechanism is discussed.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Vorob'evy gory, Moscow, 119899, Russia

    N. Sh. Pirkuliev, N. G. Akhmedov & N. S. Zefirov

  2. Russian Academy of Sciences, Chernogolovka, Institute of Physiologically Active Substances, Moscow oblast, Russia

    N. Sh. Pirkuliev, V. K. Brel & N. S. Zefirov

  3. Rasulzade Baku State University, Baku, Azerbaidjan

    A. M. Magerramov & N. G. Shykhaliev

Authors
  1. N. Sh. Pirkuliev
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  2. V. K. Brel
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  3. N. G. Akhmedov
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  4. A. M. Magerramov
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  5. N. G. Shykhaliev
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  6. N. S. Zefirov
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Pirkuliev, N.S., Brel, V.K., Akhmedov, N.G. et al. Reactions of [Fluoro(methylsulfonyloxy)iodo]benzene: II. Reaction of [Fluoro(sulfonyloxy)iodo]benzene with Acyclic Olefins. Russian Journal of Organic Chemistry 37, 683–686 (2001). https://doi.org/10.1023/A:1012447800929

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  • DOI: https://doi.org/10.1023/A:1012447800929

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