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Reactions of Aromatic Nitro Compounds: LXXIV. Azo Coupling of Anionic Nitroarene σ-Complexes with Aromatic Diazo Compounds. Effect of Reaction Conditions on the Yield of Nitroazobenzenes

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Abstract

Effect of a number of factors on the yield of nitroazobenzenes in the reaction of 4-nitro- and 4-dimethylaminobenzenediazonium tetrafluoroborates with anionic σ adducts derived from 1,3-dinitrobenzene was studied. Conditions were found which allow nitroazobenzenes to be prepared in 80-90% yield.

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Authors and Affiliations

  1. Tolstoy Tula State Pedagogical University, pr. Lenina 125, Tula, 300026, Russia

    N. I. Blokhina, I. V. Shakhkel'dyan, Yu. M. Atroshchenko, E. N. Alifanova, S. S. Gitis, A. Ya. Kaminskii & D. N. Moiseev

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  1. N. I. Blokhina
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  2. I. V. Shakhkel'dyan
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  3. Yu. M. Atroshchenko
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  4. E. N. Alifanova
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  5. S. S. Gitis
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  6. A. Ya. Kaminskii
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  7. D. N. Moiseev
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Blokhina, N.I., Shakhkel'dyan, I.V., Atroshchenko, Y.M. et al. Reactions of Aromatic Nitro Compounds: LXXIV. Azo Coupling of Anionic Nitroarene σ-Complexes with Aromatic Diazo Compounds. Effect of Reaction Conditions on the Yield of Nitroazobenzenes. Russian Journal of Organic Chemistry 37, 401–403 (2001). https://doi.org/10.1023/A:1012440710073

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  • DOI: https://doi.org/10.1023/A:1012440710073

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