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New Reagents for Determination of the Quantum Efficiency of Singlet Oxygen Generation in Aqueous Media

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Abstract

Water-soluble anthracene derivatives containing carboxy, dihydroxyphosphinyl, or pyridinium fragments bound via methylene groups to 9- and 10-carbon atoms were prepared, and their spectra, solubility, and reactivity toward singlet oxygen were studied. Using sodium α,α'-(anthracene-9,10-diyl)bis(methyl- malonate) as acceptor, it is possible to determine the quantum efficiency of singlet oxygen generation in aqueous solutions and in microheterogeneous media in the presence of biomacromolecules.

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Authors and Affiliations

  1. Research Institute of Organic Intermediates and Dyes, Moscow, Russia

    N. A. Kuznetsova, N. S. Gretsova, O. A. Yuzhakova, V. M. Negrimovskii, O. L. Kaliya & E. A. Luk'yanets

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  1. N. A. Kuznetsova
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  2. N. S. Gretsova
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  3. O. A. Yuzhakova
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  4. V. M. Negrimovskii
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  5. O. L. Kaliya
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  6. E. A. Luk'yanets
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Kuznetsova, N.A., Gretsova, N.S., Yuzhakova, O.A. et al. New Reagents for Determination of the Quantum Efficiency of Singlet Oxygen Generation in Aqueous Media. Russian Journal of General Chemistry 71, 36–41 (2001). https://doi.org/10.1023/A:1012369120376

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