Abstract
A synthetic approach to β-(chloromethyl)furans with free 2, 5 positions is developed. It isshown that these compounds enter the Michaelis-Becker reaction to form usual phosphorylation products.With 3,4-bis(diethoxyphosphorylmethyl)furan, two conformers with different chemical shifts of phosphorus nuclei and PCH2 protons were detected.
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Pevzner, L.M. Synthesis of 3,4-Disubstituted Phosphorus-containing Furans with Free 2 and 5 Positions. Russian Journal of General Chemistry 71, 525–527 (2001). https://doi.org/10.1023/A:1012366731221
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DOI: https://doi.org/10.1023/A:1012366731221