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Steric Factors in Liquid-Phase Oxidation of Olefins with iso Structure

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Abstract

Products of liquid-phase oxidation of 2-methyl-2-butene and 2-methyl-2-pentene were studied by NMR and IR spectroscopy. Steric hindrances in liquid-phase oxidation of olefins with iso structure were shown to arise from branching of the alkyl group at the α-carbon atom.

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Authors and Affiliations

  1. Yaroslavl State Technical University, Moskovskii pr. 88, Yaroslavl, 150023, Russia

    A. V. Voronenkov, N. A. Simonov, O. P. Yablonskii, S. G. Koshel' & V. V. Voronenkov

  2. “Yarsintez Research Institute” Public Corporation, Yaroslavl, Russia

    A. V. Voronenkov, N. A. Simonov, O. P. Yablonskii, S. G. Koshel' & V. V. Voronenkov

Authors
  1. A. V. Voronenkov
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  2. N. A. Simonov
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  3. O. P. Yablonskii
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  4. S. G. Koshel'
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  5. V. V. Voronenkov
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Voronenkov, A.V., Simonov, N.A., Yablonskii, O.P. et al. Steric Factors in Liquid-Phase Oxidation of Olefins with iso Structure. Russian Journal of Organic Chemistry 37, 318–320 (2001). https://doi.org/10.1023/A:1012359819642

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  • DOI: https://doi.org/10.1023/A:1012359819642

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