The process and results of a thermodynamic analysis of C8 isomer formation upon the alkylation of isobutene by olefins using thermobaric dependence and an information model are presented. The experimental data were used to determine the probability of reaction in the 1-3 MPa pressure range. No significant change in the Gibbs energy was found to occur at pressures above 1 MPa.
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 6, pp. 17 – 22, November – December, 2016.
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Khamzin, Y.A., Shiriyazdanov, R.R., Trapeznikova, E.F. et al. Thermodynamic Analysis of the Formation of C8 Isomers in the Alkylation of Isobutane by Olefins. Chem Technol Fuels Oils 52, 646–655 (2017). https://doi.org/10.1007/s10553-017-0756-z
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DOI: https://doi.org/10.1007/s10553-017-0756-z